以离子液体氯化-1-十二烷基甲基咪唑（C12 mimCl）为表面活性剂，甲基丙烯酸甲酯（MMA）和丙烯酰胺（AM）混合物为油相构筑的反相微乳液合成AgCl纳米粒子。通过微乳液聚合制备AgCl／poly（MMA—co—AM）杂化膜，用于苯-环己烷混合物的渗透汽化分离。利用紫外-可见吸收光谱（UV—Vis）和透射电镜（TEM）分析AgCl纳米粒子的形貌及结构，利用XRD和SEM分析了杂化膜中AgCl粒子的形貌及结构，通过杂化膜的苯-环已烷混合物（质量分数50％，30℃）的渗透汽化实验分析了杂化膜的分离性能。结果表明：纳米AgCl粒子的平均粒径和粒子数随微乳液中AgNO3浓度（CAgNO3）的增大明显增加；增加微乳液中C122mimCl浓度（CC12mimCl），有利于形成数量较多、平均粒径较小的纳米AgCl粒子；AgCl／poly（MMA—co—AM）杂化膜中AgCl粒子粒径较小，且均匀分散于poly（MMA—co—AM）基材中；随着CAgNO3的增加，杂化膜的渗透通量明显增大，分离因子先增大后减小；而随CC12mimCl的增加，杂化膜的分离因子持续增大，渗透通量表现出先增大后减小的趋势；杂化膜的分离因子最高可达5．0，渗透通量约为490g·m^-2·h^-1，表现出较好的分离性能。
Nanoparticles of AgCl were synthesized in W/O reverse microemulsion using ionic liquid 1 - dodecyl - 3 -methyl imidazoium chloride(Cl2mimCl) as surfactant, methyl methacrylate(MMA)-acrylamide(AM) mixture as oil phase. And then AgCl/poly(MMA-co-AM) hybrid membranes were prepared by microemulsion polymerization for separation of benzenecyclohexane (mass fraction 50%) mixture by pervaporation at 30 ℃. The effect of concentration of surfactant (CC12mimCl) and salt (CAgNO3 ) on formation and morphology of AgCl nanoparticles were studied by ultravioletvisible spectrum and transmission electron microscopy(TEM). The structures of hybrid membranes were characterized by XRD and SEM. The pervaporation performance of the hybrid membranes was studied. The results show that the number and average size of AgCl nanoparticles increase significantly with the increase of CAgNO3 , and the number of AgCl nanoparticles increases but the average sizes decreases with the increase of CC12mimCl. AgCl nanoparticles maintain well dispersion with small size in AgClI/poly(MMA-co-AM) hybrid membranes. With the increase of CAgNO3 , the flux of the hybrid membranes increases significantly, and the separation factor of hybrid membranes for benzene - cyclohexane mixtures increases first and then decreases. When CC12mimCl rising, the separation factor increases continuously, and the flux increases first and then decreases. The maximum separation factor of hybrid membrane for benzene - cyclohexane mixtures reaches 5.0 and the flux of the hybrid membrane is 490g·m^-2·h^-1, which demonstrates good separation property.
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