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利用超声波将多壁碳纳米管(CNTs)分散于苯胺盐酸溶液体系中,以过硫酸铵((NH4)2S2O8)为氧化荆,原位聚合法制备碳纳米管/聚苯胺纳米复合材料(CNTs/PANI).采用扫描电子显微镜(SEM)、傅立叶变换红外光谱(FT-IR)、四探针电导率测试仪对复合材料进行表面观察、结构测定和电性能表征.结果表明,复合材料为核.壳结构,碳纳米管和聚苯胺问存在相互作用,其电导率随碳纳米管含量的增加而增加.

参考文献

[1] Erik T. Thostenson;Zhifeng Ren;Tsu-Wei Chou .Advances in the science and technology of carbon nanotubes and their composites: a review[J].Composites science and technology,2001(13):1899-1912.
[2] Umar Khan;Kevin Ryan;Werner J. Blau .The effect of solvent choice on the mechanical properties of carbon nanotube-polymer composites[J].Composites science and technology,2007(15/16):3158-3167.
[3] Huseyin Zengin;Wensheng Zhou;Jianyong Jin;Richard Czerw;Dennis W. Smith Jr.;Luis Echegoyen;David L. Carroll;Stephen H. Foulger;John Ballato .Carbon Nanotube Doped Polyaniline[J].Advanced Materials,2002(20):1480-1483.
[4] Mawhinney DB.;Kuznetsova A.;Yates JT.;Liu J.;Smalley RE.;Naumenko V. .Infrared spectral evidence for the etching of carbon nanotubes: Ozone oxidation at 298 K[J].Journal of the American Chemical Society,2000(10):2383-2384.
[5] Liu ZF.;Zhu T.;Hou SF.;Ying LZ.;Shi ZJ.;Gu ZN.;Shen ZY. .Organizing single-walled carbon nanotubes on gold using a wet chemical self-assembling technique[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(8):3569-3573.
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