合成了一种丙烯酸酯类向列相液晶单体LCM及其高分子LCP,采用溶液共混制备了不同配比的MCNT/LCP复合材料,其结构与性能通过FT-IR、1H-NMR、DSC、POM、SEM和荧光光谱表征.LCM与LCP均呈现向列相的线状织构与纹影织构,LCM的熔点与清亮点分别为149.2℃与172.1℃,而LCP的玻璃化温度与清亮点分别是53.1℃与239.4℃.多壁碳纳米管(MCNT)的加入并不改变LCP的液晶相类型与织构,当MCNT的质量分数从0.05％增加到5％时,对应复合材料的清亮点从255.9℃上升到270.1℃,而玻璃化温度呈现先升高后降低的趋势.此外,质量分数在1％以下的MCNT能均匀分散在LCP中,而且沿着液晶的矢量方向排列,起到了稳定液晶相的作用,但当MCNT质量分数为3％时,会出现明显的团聚现象.
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