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Supported PtRu/C catalysts used in direct methanol fuel cells (DMFCs) were prepared by a new modified polyol method.Transmission electron microscopy (TEM),X-ray diffraction (XRD) and cyclic voltammograms (CVs) were carried out to characterize the morphology,composition and the electrochemical properties of the PtRu/C catalyst.The results revealed that the PtRu nanoparticles with small average particle size (≈2.5 nm),and highly dispersed on the carbon support.The PtRu/C catalyst exhibited high catalytic activity and anti-poisoned performance than that of the JM PtRu/C.It is imply that the modified polyol method is efficient for PtRu/C catalyst preparation.

参考文献

[1] Pozio A;De Francesco M .Comparison of high surface Pt/C catalysts by cyclic voltammetry[J].Journal of Power Sources,2002,105:13-19.
[2] Petrow H G;Allen R G .Finelyparticulated colloidal platinum compound and sol for producing the same,and method of preparation[P].US.Patent,4044193,1977-09-22.
[3] Prabhuram J;Wang X C;Hui L et al.Synthesis and characterization of surfactant-stabilized Pt/C nanocatalysts for fuel cellapplications[J].Journal of Physical Chemistry B,2003,107:11057-11064.
[4] Yasuda K.;Nishimura Y. .The deposition of ultrafine platinum particles on carbon black by surface ion exchange - increase in loading amount[J].Materials Chemistry and Physics,2003(3):921-928.
[5] L. Xiong;A. M. Kannan;A. Manthiram .Pt-M (M=Fe, Co, Ni and Cu) electrocatalysts synthesized by an aqueous route for proton exchange membrane fuel cells[J].Electrochemistry communications,2002(11):898-903.
[6] Verma L K .Studies on methanol fuel cell[J].Journal of Power Sources,2000,86(1/2):464-468.
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