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通过共沉淀法制备出PyDDP表面修饰的二硫化钼纳米微粒。采用FT-IR、TEM、元素分析对产物组成和结构进行表征,并考察了其在有机溶剂中的分散性。结果表明:所得表面修饰MoS2纳米微粒尺寸在30 nm~50 nm之间,其在氯仿、丙酮和基础油中具有良好的分散性。利用四球极压抗磨试验考察了其摩擦学性能,磨损试验结果表明表面修饰的MoS2纳米微粒具有良好的抗磨、减摩性能。

Molybdenum disulfide nanoparticles surface-modified by PyDDP was prepared with coprecipitation method used. The composition and structures were characterized by FT-IR,TEM and elemental analysis. The dis-persion was studied in the organic solvent . The results showed that the particle diameter of the prepared MoS2 nano-particles was in a range of 30nm~50nm. The dispersibility in chloroform,acetone and the base oil was good. Their tribologiy behavior was evaluated with a four-ball tester. The tribology results showed that the prepared MoS2 nanop-articles is an oil addition exhibited good friction-reduction and antiwear properties.

参考文献

[1] 王淮英,朱红,康晓红,王滨,朱磊.表面修饰MoS2纳米微粒的合成及摩擦学性能[J].北京交通大学学报(自然科学版),2005(06):55-57.
[2] 张泽抚;刘维民;薛群基.钼化合物润滑材料的摩擦学应用与应用研究发展现状[J].摩擦学学报,1998(12):377-382.
[3] 高利华,李聚源,付丽芳,张耀君,张莉.稀土氟化物纳米润滑油添加剂的合成及应用[J].西安石油大学学报(自然科学版),2006(03):83-86.
[4] 王洪斌,孙永力,刘平,丁伟.硫磷酸系列润滑油无灰添加剂的合成与应用[J].润滑油,2001(05):35-39.
[5] 马少华.轻稀土氟化物纳米微粒的制备及其抗磨性能评价[J].应用化工,2011(11):1976-1979.
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