研究了添加剂硫脲(TU)对低温碱性化学镀镍的镀速和镀层质量的影响.结果表明,随着硫脲加入量增大,化学镀镍速率先减小后增大,其适宜加入量为1 mg/L;硫脲对H+的还原具有抑制作用而对镀层组成影响很小.它的添加使镀层晶粒更为细致均匀,镀层更平滑,孔隙率更低;镀层以Ni为主并含少许Ni5P4,硫脲使Ni结晶峰得到增强.少量的硫脲会促进极化进而减缓镍的沉积,但加入量增加时,则增加去极化效应而加速镍的沉积.
参考文献
[1] | Elansezhian R,Ramamoorthy B,Nair P K.Effect of surfactants on the mechanical properties of electroless (Ni-P) coating[J].Surf.Coat.Technol.,2008,203(5-7):709 |
[2] | 石西昌,杨慧兰,肖湘等.AZ31镁合金表面化学镀镍工艺研究[J].腐蚀科学与防护技术,2009,21(4):370 |
[3] | 肖伟,单大勇,陈荣石.熔模铸造ZA93镁合金的化学镀镍工艺研究[J].中国腐蚀与防护学报,2012,32(2):90 |
[4] | 邹建平.中温酸性化学镀镍-磷合金工艺的研究[D].昆明:昆明理工大学,2004 |
[5] | 崔作兴,顾云飞,邵忠财等.镁合金化学转化膜上化学镀镍的研究[J].腐蚀科学与防护技术,2010,22(1):74 |
[6] | Bi H,Kou K C,Rider A E,et al.Low-phosporous nickel-coated carbon microcoils:Controlling microstructure through an electroless plating process[J].Appl.Surf.Sci.,2009,255(15):6888 |
[7] | Cheon S Y,Park S Y,Rhym Y M,et al.The effect of bath conditions on the electroless nickel plating on the porous carbon substrate[J].Curr.Appl.Phys.,2011,11(3):790 |
[8] | Li L B,An M Z,Wu G H.Electroless deposition of nickel on the surface of silicon carbide/aluminum composites in alkaline bath[J].Mater.chem.Phys.,2005,94(1):159 |
[9] | Xiao F X,Shen X N,Xie J P,et al.Electroless deposition of nickel on the surface of silicon carbide crucible from alkaline bath[J].ADV.MAT.RES.,2012,399-401:2049 |
[10] | Zheng Y J,Xiao F X,Yi D Q,et al.Preparation of salt-based colloid palladium of high concentration[J].Trans.Nonferrous Met.Soc.China,2005,15(1):190 |
[11] | Li L B,An M Z.Electroless nickel-phosphorus plating on SiCp/Alcomposite from acid bath with nickel activation[J].J.Alloy.Compd,2008,461 (1-2):85 |
[12] | Balaraju J N,Jahana S M,Jain A,et al.Structure and phase transformation behavior of electroless Ni-P alloys containing tin and tungsten[J].J.Alloy.Compd.,2007,436(1-2):319 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%