利用界面聚合反应,以过硫酸铵为氧化剂制备了磺基水杨酸掺杂的聚苯胺纳米棒,以红外光谱(FT-IR)、紫外光谱(UV-Vis)、透射电子显微镜(TEM)、X射线衍射(XRD)等测试对产物进行了表征;结果表明,磺基水杨酸/苯胺(SSA/AN)比率和有机相会影响产物形貌,进一步研究证明当有机相密度小于水时,产生的聚苯胺具有更好的棒状形貌、结晶性、产率和电导率.
参考文献
[1] | Paul R.K.;Pillai C.K.S. .Melt/solution processable conducting polyaniline with novel sulfonic acid dopants and its thermoplastic blends[J].Synthetic Metals,2000(1):27-35. |
[2] | Blinova NV;Stejskal J;Trchova M;Prokes J;Omastova M .Polyaniline and polypyrrole: A comparative study of the preparation[J].European Polymer Journal,2007(6):2331-2341. |
[3] | Skotheim T A;Elsenbaumer R L;Reynolds J R.Handbook of Conducting Polymers[M].New York,USA:Marcel Dekker,Inc,1986 |
[4] | Xing Shuangxi;Zhao Chun et al.[J].Solid-State Electronics,2006,50:1629-1633. |
[5] | McGovern ST;Spinks GM;Wallace GG .Micro-humidity sensors based on a processable polyaniline blend[J].Sensors and Actuators, B. Chemical,2005(2):657-665. |
[6] | Mandir Z;Duid L .[J].Journal of Electroanalytical Chemistry,1996,403:133-141. |
[7] | Hu Chi Chang;Chu Chien-How .[J].Materials Chemistry and Physics,2000,65:329-338. |
[8] | Mu Shaolin .[J].Electrochimica Acta,2007,52:7827-7834. |
[9] | Gong Jian;Cui Xiujun;Xie Zhongwei et al.[J].Synthetic Metals,2002,129:187-192. |
[10] | Yu Qiaozhen;Shi Minmin;Deng Meng et al.[J].Materials Science and Engineering B,2008,150:70-76. |
[11] | Zhang Lixia;Zhang Lijiuan;Wana Meixiang .[J].European Polymer Journal,2008,44:2040-2045. |
[12] | Guo Y;Zhou Y .[J].European Polymer Journal,2007,43:2292-2296. |
[13] | Jeevananda T;Lee J H et al.[J].Materials Letters,2008,62:3995-3998. |
[14] | Dallas P;Stamopoulos D;Boukos N et al.[J].Polymer,2007,48:3162-3169. |
[15] | Huang J;Kaner R B .[J].Chemical Communications,2006,4:367-376. |
[16] | 郑剑锋,赵江红,宋金玲,朱珍平.水相/有机相界面扩散控制聚苯胺纳米线生长[J].化工新型材料,2009(05):40-42. |
[17] | Xing Shuangxi;Zhen Hongwei;Zhao Guoku .[J].Synthetic Metals,2008,158:59-63. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%