在非真空熔炼条件下采用工业纯原材料和负压铜模吸铸法制备Mg65Cu25Y10-xNdx(x=0,2,4,6,8,10)棒状试样,利用差示扫描量热(DSC)和X射线衍射(XRD)等方法分析Nd对Mg-Cu-Y-Nd非晶合金玻璃形成能力的影响.结果表明:Nd的含量(x)为0,4,6成分的合金试样具有完全非晶态组织,且x=4时具有最大的玻璃形成能力,其约化玻璃转变温度(Trg)为0.592,过冷液相区宽度(ΔTx)高达66 K;当x为2,8,10时,由于合金成分明显偏离共晶成分,玻璃形成能力降低,试样只含有少量非晶,且主要呈晶体组织特征.
参考文献
[1] | 张曙光,胡捷,朱学新,王发东,徐骏,石力开.Zr基非晶合金在过冷液相区静液挤压的变形行为及结构[J].中国有色金属学报,2006(04):631-637. |
[2] | Inoue A .High strength bulk amorphous alloys with low critical cooling rates[J].Materials Transactions-Japan Institute of Metals,1995,36:866-875. |
[3] | Kato A;Inoue A .Consolidation and their mechanical properties of amorphous Mg87.5Cu5Y7.5 and Mg70Ca10Al20 powders produced by high press gas atomization[J].Materials Transactions-Japan Institute of Metals,1995,36(07):977-981. |
[4] | Inoue A;Kato A;Zhan T;Kim S .Mg-Cu-Y amorphous alloys with high mechanical strengths produced by a high-pressure die casting method[J].Materials Transactions JIM,1992,33:937-945. |
[5] | 门华,徐坚.Mg-CU-Zn-y块体金属玻璃的形成[J].金属学报,2001(12):1243-1246. |
[6] | A. Inoue .Stabilization and high strain-rate superplasticity of metallic supercooled liquid[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,1999(2):171-183. |
[7] | Kenji Amiya;Akihisa Inoue .Preparation of Bulk Glassy Mg_(65)Y_(10)Cu_(15)Ag_5Pd_5 Alloy of 12 mm in Diameter by Water Quenching[J].Materials transactions,2001(3):543-545. |
[8] | Ma H.;Ma E.;Xu J. .A new Mg65Cu7.5Ni7.5Zn5Ag5Y10 bulk metallic glass with strong glass-forming ability[J].Journal of Materials Research,2003(10):2288-2291. |
[9] | 吴树森;毛有武;万里;罗吉荣 刘伟 .金属玻璃熔体的铸造成形方法及其装置[P].CN 1803342,2005-10-02. |
[10] | 李振寰.元素性质数据手册[M].石家庄:河北人民出版社,1985 |
[11] | De Boer F R;Boom R;Mattens W C M.Cohesion in metals[M].Amsterdam:North-Holland;New York,USA:Elsevier Scientific Pub Co,1988:344. |
[12] | Yuan GY;Amiya K;Inoue A .Structural relaxation, glass-forming ability and mechanical properties of Mg-Cu-Ni-Gd alloys[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2005(8/9):729-735. |
[13] | Tang M B;Zhao D Q;Pan M X;Wang W H .A paramagnetic Nd60Cu20Ni10Al10 alloy with high glass-forming ability[J].Journal of Physics D:Applied Physics,2004,37:973-975. |
[14] | Greer A L .Materials science-confusion by design[J].Nature,1993,366:303-304. |
[15] | 孙国元,陈光.Mg基大块金属玻璃的形成能力与形成机制[J].有色金属,2004(02):22-26. |
[16] | X. Hu;S. C. Ng;Y. P. Feng;Y. li .Glass forming ability and in-situ composite formation in Pd-based bulk metallic glasses[J].Acta materialia,2003(2):561-572. |
[17] | Busch R.;Johnson WL.;Liu W. .Thermodynamics and kinetics of the Mg65Cu25Y10 bulk metallic glass forming liquid[J].Journal of Applied Physics,1998(8):4134-4141. |
[18] | X. H. Lin;W. L. Johnson;W. K. Rhim .Effect of Oxygen Impurity on Crystallization of an Undercooled Bulk Glass Forming Zr-Ti-Cu-Ni-Al Alloy[J].Materials transactions,1997(5):473-477. |
[19] | Liu W Y;Zhang H F;Hu Z Q;Wang H .Formation and mechanical properties of Mg65Cu25Er10 and Mg65Cu15Ag10Er10 bulk amorphous alloys[J].Journal of Alloys and Compounds,2005,397:202-205. |
[20] | Xi XK;Wang RJ;Zhao DQ;Pan MX;Wang WH .Glass-forming Mg-Cu-RE (RE = Gd, Pr, Nd, Tb, Y, and Dy) alloys with strong oxygen resistance in manufacturability[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2004(3):105-109. |
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