采用熔融-急冷法制备了(100-x)GeS2-xSb2S3(x=10%、15%和20%)系列硫系玻璃,测试了样品的折射率、从可见到近红外的透过特性.采用Z-扫描方法测试了样品的三阶非线性特性,分析了Sb2S3的含量对玻璃的线性折射率,透过率和三阶非线性性能的影响.结果表明样品的线性折射率、非线性折射率n2、非线性吸收系数β以及三阶非线性光学极化率χ(3)随着Sb2S3的含量增加而增大,Sb2S3物质的量含量为20%的样品在800 nm处的三阶非线性折射率n2和非线性吸收系数β分别为:n2=3.27×10-10 esu和β= 31.5 cm/Gw.
参考文献
| [1] | K. S. Bindra;H. T. Bookey;A. K. Kar;B. S. Wherrett;X. Liu;A. Jha .Nonlinear optical properties of chalcogenide glasses: Observation of multiphoton absorption[J].Applied physics letters,2001(13):1939-1941. |
| [2] | Kanbara H;Fujiwara S;Tanaka K;Nasu H;Hirao K;KYOTO UNIV FAC ENGN KYOTO 606 JAPAN. .Third-order nonlinear optical properties of chalcogenide glasses[J].Applied physics letters,1997(8):925-927. |
| [3] | Gomes A S L;Falcao Filho E L;De araujo C B et al.Third-order nonlinear properties of bismuth-borate glasses measured by conventional and thermally managed eclipse Z scan[J].Journal of Applied Physics,2007,101:033115. |
| [4] | Bureau B;Zhang XH;Smektala F;Adam JL;Troles J;Ma HL;Boussard-Pledel C;Lucas J;Lucas P;Le Coq D .Recent advances in chalcogenide glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2004(0):276-283. |
| [5] | Petit L;Carlie N;Adamietz F;Couzi M;Rodriguez V;Richardson KC .Correlation between physical, optical and structural properties of sulfide glasses in the system Ge-Sb-S[J].Materials Chemistry and Physics,2006(1):64-70. |
| [6] | Kotsalas IP.;Raptis C.;Vlcek M.;Frumar M.;Papadimitriou D. .Raman study of photostructural changes in amorphous GexSb0.4S0.6[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1/2):85-91. |
| [7] | Farg ESM .Optical properties of amorphous Ge30-xSbxS70 films[J].Optics & Laser Technology,2006(1):14-18. |
| [8] | L. Petit;N. Carlie;K. Richardson;A. Humeau;S. Cherukulappurath;G. Boudebs .Nonlinear optical properties of glasses in the system Ge/Ga--Sb--S/Se[J].Optics Letters,2006(10):1495-1497. |
| [9] | Sheik-Bahae M.;Said A.A. .Sensitive measurement of optical nonlinearities using a single beam[J].IEEE Journal of Quantum Electronics: A Publication of the IEEE Quantum Electronics and Applications Society,1990(4):760-769. |
| [10] | Ali QM;Palanisamy PK .Investigation of nonlinear optical properties of organic dye by Z-scan technique using He-Ne laser[J].Optik: Zeitschrift fur Licht- und Elektronenoptik: = Journal for Light-and Electronoptic,2005(11):515-520. |
| [11] | 泉谷澈郎;杨淑清.光学玻璃与激光玻璃开发[M].北京:兵器工业出版社,1996:229-232. |
| [12] | Phillips J C .Topology of covalent non-crystalline solids I:short range order in chalcogenide alloys[J].Journal of Non-Crystalline Solids,1979,34:153. |
| [13] | Phillips J C .Vibrational thresholds near critical average coordination in alloy network glasses[J].Physical Review B:Condensed Matter,1985,31:8157-8163. |
| [14] | Farid AM;Fouad SS;Ammar AH .The structural properties of GexSb40-xSe60 system[J].Journal of Materials Science. Materials in Electronics,2005(2):97-101. |
| [15] | Giridhar A;Mahaevan S .Topological transitions and chemical ordering in Ge-In-Se glasses[J].Journal of Non-Crystalline Solids,1991,134:94-99. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%