目前制备CZTS薄膜太阳电池的缓冲层绝大多数采用硫酸镉作为镉源.本文将主要介绍用醋酸镉((Ch3COO)2Cd)、氯化镉(CdCl2)和硝酸镉(Cd(NO3)2)和硫酸镉(CdSO4)四种不同的镉源制备硫化镉薄膜.通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)和紫外可见分光光度计对硫化镉薄膜的结构、表面形貌和光学性能进行分析研究.分析结果表明以硝酸镉为镉源制备的硫化镉薄膜最适合作为缓冲层使用.将不同镉源制备的硫化镉薄膜作为CZTS薄膜电池的缓冲层,制备出的电池效率分别为:1.83％((Ch3COO)2Cd)、2.89％(CdCl2)、3.4％(Cd(NO3)2)、3.19％(CdSO4).
参考文献
| [1] | Susanne Siebentritt.Why are kesterite solar cells not 20% efficient?[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2013May 15(May 15):1-4. |
| [2] | Natalia Maticiuc;Jaan Hiie;Taavi Raadik;Aleksandr Graf;Aleksei Gavrilov.The role of Cl in the chemical bath on the properties of CdS thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2013May 15(May 15):184-187. |
| [3] | Boieriu P.;Adriaens A.;Xin Y.;Browning ND.;Sivananthan S.;Sporken R..SIMS and XPS characterization of CdS/CdTe heterostructures grown by MBE[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,20000(0):975-979. |
| [4] | 王银海;许彦旗;蔡维理;牟季美.一种新的电化学方法制备CdS纳米线阵列[J].物理化学学报,2002(10):943-946. |
| [5] | 曹萌;吴杰;孙艳.酸性条件下水浴沉积时间对硫化镉薄膜特性的影响[J].上海有色金属,2010(4):163-166. |
| [6] | Shin, S.W.;Pawar, S.M.;Park, C.Y.;Yun, J.H.;Moon, J.-H.;Kim, J.H.;Lee, J.Y..Studies on Cu_2ZnSnS_4 (CZTS) absorber layer using different stacking orders in precursor thin films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,201112(12):3202-3206. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%