欢迎登录材料期刊网

材料期刊网

高级检索

中低温化是目前固体氧化燃料电池研究的主要方向,影响其发展的主要问题是电解质及阴极材料的研制.浸渗法制备复合阴极能够显著提高电池在中低温下的电化学性能和效率,是目前研究的热点之一.本文介绍了近年来采用具有催化活性的电极材料、贵金属、氧离子传导材料等作为浸渗剂制备复合阴极的研究现状,并对其发展方向进行了展望.

参考文献

[1] Tal Z. Sholklapper;Chun Lu;Craig P. Jacobson .LSM-Infiltrated Solid Oxide Fuel Cell Cathodes[J].Electrochemical and solid-state letters,2006(8):A376-A378.
[2] Teruhisa Horita;Katsuhiko Yamaji;Natsuko Sakai;Harumi Yokokawa;Andre Weber;Ellen Ives-Tiffee .Oxygen reduction mechanism at porous La_(1-x)Sr_xCoO_(3-d) cathodes/La_0.8Sr_0.2Ga_0.8Mg_0.2o_2.8 electrolyte interface for solid oxide fuel cells[J].Electrochimica Acta,2001(12):1837-1845.
[3] Mineshige A;Fujii S;Ogumi Z;Inaba M;Yao T;Kobune M .METAL-INSULATOR TRANSITION AND CRYSTAL STRUCTURE OF La1-xSrxCoO3 AS FUNCTIONS OF Sr-CONTENT, TEMPERATURE, AND OXYGEN PARTIAL PRESSURE[J].International Journal of Quantum Chemistry,1999(2):374-381.
[4] Figueiredo FM.;Frade JR.;Marques FMB.;Labrincha JA. .REACTIONS BETWEEN A ZIRCONIA-BASED ELECTROLYTE AND LACOO3-BASED ELECTRODE MATERIALS[J].Solid state ionics,1997(1):343-349.
[5] Armstrong T J;Rich J G .Anode-supported solid oxide fuel cells with La0.6Sr0 4CoO3-λ-Zr0 84Y0 16O2-δ composite cathodes fabricated by an infiltration method[J].Journal of the Electrochemical Society,2006,152(03):A515-A520.
[6] Huang YY;Ahn K;Vohs JM;Gorte RJ .Characterization of Sr-doped LaCoO3-YSZ composites prepared by impregnation methods[J].Journal of the Electrochemical Society,2004(10):A1592-A1597.
[7] Sase M;Ueno D;Yashiro K et al.Interfacial reaction and electrochemical properties of dense (La,Sr) CoO3-δ cathode on YSZ (100)[J].J Physical and Chemistry of Solids,2005,66:343-348.
[8] Jing Chen;Fengli Liang;Lina Liu;Sanping Jiang;Bo Chi;Jian Pu;Jian Li .Nano-structured (la, Sr)(co, Fe)o_3 + Ysz Composite Cathodes For Intermediate Temperature Solid Oxide Fuel Cells[J].Journal of Power Sources,2008(2):586-589.
[9] Wang WS;Gross MD;Vohs JM;Gorte RJ .The stability of LSF-YSZ electrodes prepared by infiltration[J].Journal of the Electrochemical Society,2007(5):B439-B445.
[10] Lou X Y;Wang S Z;Liu Z.Improving La0.6Sr0.4Co0.2Fe0.8O3 cathode performance by infiltration of a Sm0.5Sr0.5CoO3 coating[J].Solid State Ionics,2009
[11] Mai A;Becker M;Assenmacher W;Tietz F;Hathiramani D;Ivers-Tiffee E;Stover D;Mader W .Time-dependent performance of mixed-conducting SOFC cathodes[J].Solid state ionics,2006(19/25):1965-1968.
[12] Simmer S P;Anderson M D;Engelhard M H .Degradation mechanisms of La-Sr-Co-Fe-O3 SOFC cathodes[J].Electrochemical and Solid State Letters,2006,9:A478-A481.
[13] Xinge Zhang;Javier Gazzarri;Mark Robertson;Cyrille Deces-Petit;Olivera Kesler .Stability Study Of Cermet-supported Solid Oxide Fuel Cells With Bi-layered Electrolyte[J].Journal of Power Sources,2008(2):1049-1055.
[14] Lee S;Miller N;Staruch M.Pr0.6Sr0.4CoO3-δ electrocatalyst for solid oxide fuel cell cathode introduced via infiltration[J].Electrochimica Acta,2011
[15] Sahibzada M.;Rudkin RA.;Kilner JA.;Benson SJ. .Pd-promoted La0.6Sr0.4Co0.2Fe0.8O3 cathodes[J].Solid state ionics,1998(Special Issue SI):285-290.
[16] Tal Z. Sholklapper;Velimir Radmilovic;Craig P. Jacobson;Steven J. Visco;Lutgard C. De Jonghe .Nanocomposite Ag-LSM solid oxide fuel cell electrodes[J].Journal of Power Sources,2008(1):206-210.
[17] Y. Sakito;A. Hirano;N. Imanishi;Y. Takeda;O. Yamamoto;Y. Liu .Silver infiltrated La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_3 cathodes for intermediate temperature solid oxide fuel cells[J].Journal of Power Sources,2008(2):476-481.
[18] Jiang SP;Wang W .Novel structured mixed ionic and electronic conducting cathodes of solid oxide fuel cells[J].Solid state ionics,2005(15/16):1351-1357.
[19] Jiang SP;Wang W .Fabrication and performance of GDC-impregnated (La,Sr)MnO3 cathodes for intermediate temperature solid oxide fuel cells[J].Journal of the Electrochemical Society,2005(7):A1398-A1408.
[20] Chen J;Liang F L;Chi B et al.Palladium and ceria infiltrated La0.8Sr0 2Co0 5Fe0 5O3 cathodes of solid oxidefuel cells[J].Journal of Power Sources,2009,194:275-280.
[21] T. Z. Sholklapper;H. Kurokawa;C. P. Jacobson .Nanostructured Solid Oxide Fuel Cell Electrodes[J].Nano letters,2007(7):2136-2141.
[22] Zhang Q S;Hirano A;Imanishi N et al.LSM cathodes infiltrated with Er2O3 stabilized Bi2O3[J].JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY,2009,6:1-5.
[23] Bo Wei;Zhe Lü;Tianshi Wei;Dechang Jia;Xiqiang Huang;Yaohui Zhang;Jipeng Miao;Werihui Su .Nanosized Ce_(0.8)Sm_(0.2)O_(1.9) infiltrated GdBaCo_2O_(5-δ) cathodes for intermediate-temperature solid oxide fuel cells[J].International journal of hydrogen energy,2011(10):6151-6159.
[24] 聂丽芳,刘俊成,张玉军.固体氧化物燃料电池LSCF-SDC纳米复合阴极制备及性能研究[J].无机化学学报,2011(10):1909-1913.
[25] Yamahara K;Jacobson CP;Visco SJ;Zhang XF;de Jonghe LC .Thin film SOFCs with cobalt-infiltrated cathodes[J].Solid state ionics,2005(3/4):275-279.
[26] John M. Vohs;Raymond J. Gorte .High-performance Sofc Cathodes Prepared By Infiltration[J].Advanced Materials,2009(9):943-956.
[27] Lee Y K;Kim J Y et al.Conditioning effects on La1-xSrxMnO3-yttria stabilized zirconia electrodes for thin-film solid oxide fuel cells[J].Journal of Power Sources,2003,115:219-228.
[28] 张全生;武田保雄 .过渡金属氧化物渗透对LSM-YSZ阴极性能的影响[J].无机材料学报,2007,23:1287-1290.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%