采取N过量,改变Sm浓度的方式,借助于溶胶-凝胶法成功制备了稀土金属Sm和无机非金属N有机结合的Sm-N-TiO2样品.研究了Sm掺杂对N-TiO2光催化剂的结构、光吸收和光催化活性的影响,并对甲基橙溶液进行降解实验.结果表明,制备的Sm-N-TiO2与未掺Sm的N-TiO2相比有较高的光催化活性.掺杂1.0%(摩尔分数)Sm,650℃焙烧4h条件下得到的样品性能最佳.
参考文献
[1] | Fujishima A;Honda K .Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37. |
[2] | Asahi R et al.Visible-light photo-catalysis in nitrogendoped titanium oxides[J].Science,2001,293:269. |
[3] | Mokawa T;Asahi R;Ohwaki T et al.Band-gap narrowing of titanium dioxide by nitrogen doping[J].Japanese Journal of Applied Physics,2001,40(6A):561. |
[4] | Shu Yin;Hiroshi Yamaki;Masakazu Komatsu;Qiwu Zhang;Jinshu Wang;Qing Tang;Fumio Saito;Tsugio Sato .Preparation of nitrogen-doped titania with high visible light induced photocatalytic activity by mechanochemical reaction of titania and hexamethylenetetramine[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(12):2996-3001. |
[5] | 秦好丽,古国榜,柳松.二氧化钛非金属氮掺杂的研究进展[J].材料导报,2005(10):12-15. |
[6] | 邓谦,李明,蔡晴,张鹏,彭振山,蔡铁军.稀土/二氧化钛催化剂的制备和光催化消除气体污染物[J].中国稀土学报,2011(02):170-177. |
[7] | LI Cui-xia,李翠霞,杨志忠,王希靖.稀土掺杂纳米TiO2光催化材料的制备和性能[J].兰州理工大学学报,2009(01):21-24. |
[8] | 梁春华 .稀土掺杂二氧化钛的制备、表征和光催化活性研究[D].杨凌:西北农林科技大学,2007. |
[9] | 丛野,肖玲,陈锋,张金龙.氮掺杂改性二氧化钛光催化剂的研究进展[J].感光科学与光化学,2007(02):147-155. |
[10] | Tetsuya Yamamoto;Hiroshi Katayama-Yoshida .Solution Using a Codoping Method to Unipolarity for the Fabrication of p-Type ZnO[J].Japanese journal of applied physics,1999(2B Pt.2):L166-L169. |
[11] | 李聪,侯清玉,张振铎,赵春旺,张冰.Sm-N共掺杂对锐钛矿相TiO2的电子结构和吸收光谱影响的第一性原理研究[J].物理学报,2012(16):397-403. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%