采用HCl水解钛酸四丁酯制备了可见光响应的氯掺杂TiO2光催化剂,并用X射线衍射线、透射电子显微镜、X射线光电子能谱(XPS)和紫外-可见漫反射吸收光谱等测试手段对其结构进行了表征.结果表明,氯元素的引入降低了无定形相向锐钛矿转变以及锐钛矿向金红石相转变的温度.300℃焙烧的氯掺杂TiO2吸收波长拓展到可见光区,且XPS证实氯元素以阴离子形式存在于TiO2晶格中.苯酚降解实验表明,在大于400 nm的可见光照射下,300℃焙烧的氯掺杂TiO2具有最佳的光催化活性,120 min时苯酚的降解率达到42.5%.
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