In order to develop a novel electric light source, the doped high-silica glass was studied on the preparation and spectroscopic properties. The porous glasses were made firstly and were then immersed in the solution containing Ce ion. Thereafter, the high-silica glasses containing Ce ion were prepared by sintering the porous preform. The spectroscopic properties were studied before and after heat-treatment in H2. The experimental results indicate that the suitable temperature schedules are the most important to prepare doped high-silica glass. The study of the spectra shows that Ce ion can be reduced to low valence state when it is heat-treated in H2. It can be used to adjust the UV cut-off wavelength of high-silica glass by changing the valence state of Ce ion.
参考文献
[1] | Peter C Schultz .Optical Absorption of the Transition Elements in Vitreous Silica[J].Journal of the American Ceramic Society,1973,57(07):309-313. |
[2] | H P Hood;M E Nordberg .Treated Borosilicate Glass[P].The United States Patent 2 106 744 |
[3] | ZHANG Zhao-yan,LI Qian-tao.The Structure and Emission Properties of SiO2 Nanometer Film Containing Ag[J].武汉理工大学学报(材料科学版)英,2001(02):34-37. |
[4] | Chen Quanqing;Gu Zhanglin;Ge Manzhen;Zhu Yon-ghua .Study on Porous Glass as Catalyzer Supporter[J].Special Glasses,1987,4(01):1-7. |
[5] | Huang Xihuai .Preparation of Porous Glass[J].Journal of the Chinese Ceramic Society(in Chinese),1989,17(01):38-44. |
[6] | Ian D Chapman;Peterborough .Ontario and Thomas H Elmer[P].Porous High Silica Glass.The United States Patent,3 485 687 |
[7] | Gu Zhenan .Study on the Spectra Attenuation and Fluor-escence Characteristic of Ce-doped Silicaglass[J].Journal of The Chinese Ceramic Society,1983,11(04):435-441. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%