本文将二维系统的Collins模型推广到二元替换式系统,求出了它的Gibbs函数和自由能,得到了决定两相平衡曲线的方程,研究了几种常见的相图,并对“雪茄形”相图作了具体计算,所得结果与三维情况十分相似。
To extend the Collins' model of two-dimensional system into binary substitutional system, its Gibbs' function and free energy may be evaluated and then the equation for determination of binary phase equilibrium curve may be obtained. Certain common phase diagrams were investigated, as well as a concrete calculation was made of the "cigar" phase diagram. The obtained results are quite analogous to the behaviour of the three-dimensional ones.
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