为改善多壁碳纳米管(MWNT)在低密度聚乙烯(LDPE)中的分散性及复合材料的界面特性,采用溴化-1-十六烷基-3-甲基咪唑基离子液体([C16min]Br)对MWNT进行表面改性,并用Raman光谱对改性效果进行了表征.将经过修饰的碳纳米管(MIL)与LDPE熔融共混得到MIL/LDPE复合材料,采用场发射扫描电子显微镜(FESEM)和阻抗分析仪(LCR)对复合材料的结构与介电性能进行了分析.结果表明,相比与MWNT/LDPE(渗流阈值为5.2%,介电常数为82,介电损耗为0.93),MIL/LDPE(渗流阈值为9.1%,介电常数为169,介电损耗为0.51)介电常数增大,介电损耗降低.并且在低温时,MIL/LDPE介电常数随温度的变化甚小,显示出良好的温度-介电常数特性.
参考文献
[1] | Zhi-Min Dang;Jin-Kai Yuan;Jun-Wei Zha;Tao Zhou;Sheng-Tao Li;Guo-Hua Hu .Fundamentals, processes and applications of high-permittivity polymer-matrix composites[J].Progress in materials science,2012(4):660-723. |
[2] | Tao Zhou;Jun-Wei Zha;Yi Hou .Surface-Functionalized MWNTs with Emeraldine Base: Preparation and Improving Dielectric Properties of Polymer Nanocomposites[J].ACS applied materials & interfaces,2011(12):4557-4560. |
[3] | Z.-M. Dang;L. Wang;Y. Yin;Q. Zhang;Q.-Q. Lei .Giant Dielectric Permittivities in Functionalized Carbon-Nanotube/ Electroactive-Polymer Nanocomposites[J].Advanced Materials,2007(6):852-857. |
[4] | Fukushima T.;Kosaka A.;Ishimura Y.;Yamamoto T.;Takigawa T.;Ishii N. Aida T. .Molecular ordering of organic molten salts triggered by single-walled carbon nanotubes[J].Science,2003(5628):2072-2074. |
[5] | Bellayer S;Gilman JW;Eidelman N;Bourbigot S;Flambard X;Fox DM;De Long HC;Trulove PC .Preparation of homogeneously dispersed multiwalled carbon nanotube/polystyrene nanocomposites via melt extrusion using trialkyl imidazolium compatibilizer[J].Advanced functional materials,2005(6):910-916. |
[6] | Subramaniam, K.;Das, A.;Steinhauser, D.;Klüppel, M.;Heinrich, G. .Effect of ionic liquid on dielectric, mechanical and dynamic mechanical properties of multi-walled carbon nanotubes/polychloroprene rubber composites[J].European Polymer Journal,2011(12):2234-2243. |
[7] | Kaleem Ahmad;Wei Pan;Sui-Lin Shi .Electrical conductivity and dielectric properties of multiwalled carbon nanotube and alumina composites[J].Applied physics letters,2006(13):133122-1-133122-3-0. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%