利用酸碱结合的方法提取出甘蔗渣纤维素,经酸水解制备甘蔗渣微晶纤维素(BCMC);以BCMC为增强材料,以生物可降解材料聚乳酸(PLA)作为基体,制备了BCMC/PLA复合膜,并对复合膜的结构、热稳定性和力学性能进行了研究。结果表明:BCMC均匀地分散于PLA基体中,没有发生明显的团聚现象;BCMC的加入增大了复合膜的结晶度;当BCMC的质量分数为5%时增强效果最佳,与纯的PLA膜相比,复合膜的起始分解温度提高了30.73℃,拉伸强度提高了50.98%,断裂伸长率提高了16.25%。
Bagasse cellulose extracted by method of combination of acid and alkali hydrolyzed to yield bagasse cellulose microcrystal (BCMC) using acid hydrolysis. The biodegradable composite films were prepared by using the bagasse cellulose microcrystal as filler and poly lactic acid (PLA) as the polymeric matrix. The structure, the mechanical properties and the thermal stability of the composite film were tested. The results show that the BCMC distributed well in the PLA matrix without obvious aggregation, adding the degree of crystallization of composite films. When the mass fraction of BCMC was 5 %, the optimized integrated performance of composite films could be gained. The initial decomposition temperature increased 30. 73 ℃, the tensile strength increased by 50. 98% and the elongation at break increased by 16. 25% compared with those of the pure PLA.
参考文献
[1] | Granja PL.;Pouysegu L.;De Jeso B.;Rouais F.;Baquey C.;Barbosa MA. .Cellulose phosphates as biomaterials. Mineralization of chemically modified regenerated cellulose hydrogels[J].Journal of Materials Science,2001(9):2163-2172. |
[2] | Jayamol George;M. S. Sreeekala;Sabu Thomas .A Review on Interface Modification and Characterization of Natural Fiber Reinforced Plastic Composites[J].Polymer engineering and science,2001(9):1471-1485. |
[3] | Dufresne A.;Vignon MR. .Improvement of starch film performances using cellulose microfibrils[J].Macromolecules,1998(8):2693-2696. |
[4] | Dufresne A.;Vignon MR.;Dupeyre D. .Cellulose microfibrils from potato tuber cells: Processing and characterization of starch-cellulose microfibril composites[J].Journal of Applied Polymer Science,2000(14):2080-2092. |
[5] | Alain Dufresne .Dynamic mechanical analysis of the interphase in bacterial polyester/cellulose whiskers natural composites[J].Composite interfaces,2000(1):53-67. |
[6] | S. Mohanty;S. K. Verma;S. K. Nayak .Dynamic mechanical and thermal properties of MAPE treated jute/HDPE composites[J].Composites science and technology,2006(3/4):538-547. |
[7] | 沈一丁,赖小娟,王磊.聚乳酸/乙基纤维素复合膜的制备及其性能[J].复合材料学报,2007(03):40-44. |
[8] | 庄韦,张建华,刘靖,张强,胡柏星,沈健.纳米TiO2/聚乳酸复合材料的制备和表征[J].复合材料学报,2008(03):8-11. |
[9] | 庄韦,贾海军,王喆,孙小强.原位聚合法制备纳米凹凸棒土/聚乳酸复合材料[J].复合材料学报,2010(04):45-51. |
[10] | Schwach G;Coudane J;Engel R;Vert M .More about the polymerization of lactides in the presence of stannous octoate[J].Journal of Polymer Science, Part A. Polymer Chemistry,1997(16):3431-3440. |
[11] | Mathew AP;Oksman K;Sain M .Mechanical properties of biodegradable composites from poly lactic acid (PLA) and microcrystalline cellulose (MCC)[J].Journal of Applied Polymer Science,2005(5):2014-2025. |
[12] | The effect of crystallization of PLA on the thermal and mechanical properties of microfibrillated cellulose-reinforced PLA composites[J].Composites science and technology,2009(7/8):1187-1192. |
[13] | 李春光,徐鹏飞,李云霞,王彦秋,林鹏,张锐.玉米秸秆微晶纤维素/聚乳酸复合膜的制备与性能[J].复合材料学报,2011(04):94-98. |
[14] | 王允圃,李积华,刘玉环,曾稳稳,杨柳,阮榕生,刘成梅,万益琴.甘蔗渣综合利用技术的最新进展[J].中国农学通报,2010(16):370-375. |
[15] | 曹勇,合田公一,吴义强.甘蔗渣纤维增强聚丙烯复合材料的制备和力学性能[J].复合材料学报,2007(06):1-6. |
[16] | 张力平,陈国伟,唐焕威.纤维素微纳晶体制备复合超滤膜材料的研究[J].北京林业大学学报,2008(04):1-6. |
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