欢迎登录材料期刊网

材料期刊网

高级检索

采用等离子体增强化学气相沉积技术通过高氢和低氢稀释层交替生长制备出多层初始晶硅薄膜,利用Raman散射、红外吸收、紫外可见吸收及I-V测量等技术分析了薄膜的微观结构、能带特征和光电导特性.结果显示,不同氢稀释层交替生长导致薄膜由非晶硅向初始晶硅结构转变,随高氢稀释层厚度的增加,薄膜微观结构有序性提高,所对应薄膜光学带隙减小,而带尾分布展宽.I-V测量显示,薄膜微观结构有序性提高和光学带隙降低的共同作用导致薄膜光敏性呈现先减小后增加趋势,然而,在高氢稀释层厚度较大时,纳米晶硅边界载流子快速复合导致薄膜光敏性的显著减小.

参考文献

[1] 郭学军,卢景霄,陈永生,张庆丰,文书堂,郑文,申陈海,陈庆东.甚高频高速沉积微晶硅薄膜的研究[J].物理学报,2008(09):6002-6006.
[2] Gope, J;Kumar, S;Parashar, A;Dixit, PN;Rauthan, CMS;Panwar, OS;Patel, DN;Agarwal, SC .Amorphous and nanocrystalline silicon made by varying deposition pressure in PECVD process[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2009(45/47):2228-2232.
[3] Parashar, A;Kumar, S;Gope, J;Rauthan, CMS;Dixit, PN;Hashmi, SA .Influence of argon dilution on growth and properties of hydrogenated nanocrystalline silicon films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2010(5):892-899.
[4] Muthmann, S.;Gordijn, A. .Amorphous silicon solar cells deposited with non-constant silane concentration[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2011(2):573-578.
[5] 郝会颖,孔光临,曾湘波,许颖,刁宏伟,廖显伯.非晶/微晶相变域硅薄膜及其太阳能电池[J].物理学报,2005(07):3327-3331.
[6] Myong, S.Y.;Kwon, S.W..Unique features of alternately hydrogen-diluted protocrystalline silicon multilayers as wide bandgap and highly stable absorbers of thin-film silicon solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2013:182-186.
[7] Zhang R;Chen XY;Zhang K;Shen WZ .Photocurrent response of hydrogenated nanocrystalline silicon thin films[J].Journal of Applied Physics,2006(10):4310-1-4310-5-0.
[8] Seung Yeop Myong;Seong Won Kwon;Michio Kondo;Makoto Konagai;Koeng Su Lim .Development of a rapidly stabilized protocrystalline silicon multilayer solar cell[J].Semiconductor Science and Technology,2006(2):L11-L15.
[9] 张世斌,廖显伯,安龙,杨富华,孔光临,王永谦,徐艳月,陈长勇,刁宏伟.非晶/微晶过渡区域硅薄膜的微区喇曼散射研究[J].物理学报,2002(08):1811-1815.
[10] G. Viera;S. Huet;L. Boufendi .Crystal size and temperature measurements in nanostructured silicon using Raman spectroscopy[J].Journal of Applied Physics,2001(8):4175-4183.
[11] Hydrogen structures and the optoelectronic properties in transition films from amorphous to microcrystalline silicon prepared by hot-wire chemical vapor deposition[J].Journal of Applied Physics,2003(7):3776-3783.
[12] Das D;Bhattacharya K .Characterization of the Si : H network during transformation from amorphous to micro- and nanocrystalline structures[J].Journal of Applied Physics,2006(10):3701-1-3701-8-0.
[13] Itoh T.;Ushikoshi K.;Nonomura S.;Nitta S.;Yamamoto K. .Characterization and role of hydrogen in nc-Si : H[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2000(Pt.A):201-205.
[14] 张林睿,周炳卿,张丽丽,李海泉.等离子体射频功率对微晶硅薄膜微结构及其特性影响[J].人工晶体学报,2013(03):418-422.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%