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聚(甲基)丙烯酸酯或丙烯酸高级酯与其它一些单体的共聚物是一类优良的油品增粘-降凝双效剂。丙烯酸十二酯与第二单体A的共聚物对润滑油有较好的降凝效果。丙烯酸十二酯与第二单体A的共聚物对润滑油也应有较好的增粘作用(即稠化能力)。用四种溶剂分别采用溶液聚合方法,用正交试验法对丙烯酸十二酯与第二单体A进行共聚试验,共聚物以1%的添加量加入到润滑油基础油中,做调合油的粘度测定,以增比粘度、粘温指数Q和粘度指数VI为考察目标,探讨丙烯酸十二酯与第二单体A共聚物对润滑油基础油的稠化能力,并找出较好的共聚条件。试验结果表明:丙烯酸十二酯与第二单体A共聚物对润滑油确有较好的增粘和改变油品粘温性能的作用,是一种增粘-降凝双效添加剂。

Poly ( methyl) acrylate or the copolymer of higher acrylic ester and other monomers is a kind of excel-lent double agent of oil viscosity and pour point. The copolymer of dedecyl acrylate and second monomer A has a better depressant effect on lubricant oil,it should also have good thickening effect. It was studied that dedecyl acry-late copolymerized with second monomer by solution polymerization method in four kinds of solvents,the copolymer was added into base oil of lubricating oil at 1 wt%,and the viscosity of blending oil was determined. We investiga-ted the viscosity effect of the copolymer synthesized by dedecyl acrylate and second monomer A on base oil of lubri-cating oil by exploring specific viscosity,viscosity temperature index Q and viscosity index VI,and found out the co-polymerization conditions. The test results show that:the copolymer of dedecyl acrylate and second monomer A has good adhesion and change the oil viscosity temperature performance on the lubricating oil,is a dual-purpose additive of oil viscosity and pour point.

参考文献

[1] 张景河.现代润滑油与燃料添加剂[M].北京:中国石化出版社,1991:236-277.
[2] 林世雄.石油炼制工程(下册,第二版)[M].北京:石油工业出版社,1988:378-395.
[3] 郭意厚.聚丙烯酸酯的合成及其降凝效果的研究[J].石油炼制,1991(06):26-32.
[4] 郑延成;李克华;张玉霞.新型降凝剂的合成与评价[J].河南化工,1992(07):11-15.
[5] 李学东;黄国雄.聚丙烯酸酯类降凝剂的最佳合成条件[J].润滑油,1999(04):28-32.
[6] 李学东;黄国雄.聚丙烯酸酯共聚物降凝剂的应用试验研究[J].润滑油,1999(03):53-55.
[7] 李学东.丙烯酸酯-第二单体A共聚竞聚率的测定及其应用[J].精细石油化工,1999(04):11.
[8] 付雪,李丹东,于海莲,王蓉辉,曹祖宾.聚丙烯酸酯降凝剂的制备及应用[J].辽宁石油化工大学学报,2006(03):12-15.
[9] 唐小华,严世强,王绍霞,周永红.丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂的制备[J].兰州大学学报(自然科学版),2009(01):69-72.
[10] 汪锡孝.试验研究方法[M].长沙:湖南科学技术出版社,1989:118-337.
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