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多壁碳纳米管独特的结构和性质(纳米尺寸、介孔结构和大比表面积)使其成为催化剂的良好载体.侧重于催化领域的应用,结合改性的多壁碳纳米管为载体的催化剂在各催化反应中的应用,综述了催化领域中多壁碳纳米管载体的改性方法,指出针对不同的催化反应需采用不同的方法或多种方法相结合对碳纳米管进行表面改性修饰.

Multi-walled carbon nanotube(MWNT) is considered to be excellent catalyst supports due to its unique structure and properties(nano-scale, mesoporous, high-surface-area). In this paper, the application of MWNT in catalysis areas is focused on and the modifying methods of MWNT as catalyst supports are summarized. Finally,the point that adopting different modified methods or several modified methods of carbon nanotube simultaneously for different catalytic reaction are emphasized.

参考文献

[1] De Jong KP.;Geus JW. .Carbon nanofibers: Catalytic synthesis and applications [Review][J].Catalysis Reviews. Science and Engineering,2000(4):481-510.
[2] Philippe Serp;Massimiliano Corrias;Philippe Kalck .Carbon nanotubes and nanofibers in catalysis[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2003(2):337-358.
[3] Jin G P;Baron R et al.Magnetically moveable bimetallic (nickel/silver) nanoparticle/carbon nanotube composites for methanol oxidation[J].New Journal of Chemistry,2009,33:107.
[4] Yang C W;Wang D L;Hu X G et al.Preparation and characterization of multi-walled carbon nanotube (MWC-NTs)-supported Pt-Ru catalyst for methanol electro-oxidation[J].Journal of Alloys and Compounds,2008,448(l-2):109.
[5] Hao Tong;Hu-Lin Li;Xiao-Gang Zhang .Ultrasonic synthesis of highly dispersed Pt nanoparticles supported on MWCNTs and their electrocatalytic activity towards methanol oxidation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(12):2424-2432.
[6] 杨春巍,胡信国,张亮,戴长松.多壁碳纳米管的超声处理对PtRu/MWCNTs电催化性能的影响[J].材料工程,2008(07):79-82,87.
[7] Li C H;Yao K F;Liang J .Influence of acid treatment on the activity of carbon nanotube-supported catalysts[J].CARBON,2003,41(04):858.
[8] Wang W D;Serp P;Kalck P et al.Visible light photode-gradation of phenol on MWNT-TiO_2 composite catalysts prepared by a modified sol-gel method[J].Journal of Molecular Catalysis A:Chemical,2005,235(1-2):194.
[9] Yang, SX;Li, X;Zhu, WP;Wang, JB;Descorme, C .Catalytic activity, stability and structure of multi-walled carbon nanotubes in the wet air oxidation of phenol[J].Carbon,2008(3):445-452.
[10] KUN YANG;WENHAO WU;QINGFENG JING .Aqueous Adsorption of Aniline, Phenol, and their Substitutes by Multi-Walled Carbon Nanotubes[J].Environmental Science & Technology: ES&T,2008(21):7931-7936.
[11] Wang W D;Serp P;Kalck P et al.Preparation and characterization of nanostructured MWCNT-TiO_2 composite materials for photocatalytic water treatment applications[J].Materials Research Bulletin,2008,43:958.
[12] Liu ZL.;Lin XH.;Lee JY.;Zhang W.;Han M.;Gan LM. .Preparation and characterization of platinum-based electrocatalysts on multiwalled carbon nanotubes for proton exchange membrane fuel cells[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(10):4054-4060.
[13] Wenzhen Li;Changhai Lian;Jieshan Qiu;Weijinag Zhou;Hongmei Han;Zhaobin Wei;Gongquan Sun;Qin Xin .Carbon nanotubes as support for cathode catalyst of a direct methanol fuel cell[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(5):791-794.
[14] Zhiming Cui;Changpeng Liu;Jianhui Liao;Wei Xing .Highly active PtRu catalysts supported on carbon nanotubes prepared by modified impregnation method for methanol electro-oxidation[J].Electrochimica Acta,2008(27):7807-7811.
[15] Zhao Y;Li C H;Yu Z X et al.Effect of microstructures of Pt catalysts supported on carbon nanotubes (CNTs) and activated carbon(AC) for nitrobenzene hydrogenation[J].Materials Chemistry and Physics,2007,103:225.
[16] Liu ZJ.;Zhou WZ.;Peng LM.;Xu ZD.;Yuan ZY. .Co/carbon-nanotube monometallic system: the effects of oxidation by nitric acid[J].Physical chemistry chemical physics: PCCP,2001(12):2518-2521.
[17] 张宁,周冬兰,朱瑜.Ni/CNTs催化剂的制备及其对甲醇气相羰基化反应的催化性能[J].催化学报,2006(07):591-595.
[18] Wang, XY;Xia, BY;Zhu, XF;Chen, JS;Qiu, SL;Li, JX .Controlled modification of multiwalled carbon nanotubes with Zno nanostructures[J].Journal of Solid State Chemistry,2008(4):822-827.
[19] Chen C S;Chen X H;Yi B et al.Znic oxide nanoparticle decorated multi-walled carbon nanotubes and their optical properties[J].Acta Materialia,2006,54:5401.
[20] Zhi-Peng Sun;Xiao-Gang Zhang;Rui-Li Liu;Yan-Yu Liang;Hu-Lin Li .A Simple Approach Towards Sulfonated Multi-walled Carbon Nanotubes Supported By Pd Catalysts For Methanol Electro-oxidation[J].Journal of Power Sources,2008(2):801-806.
[21] Lu X;Imae T .Dendrimer-mediated synthesis of water-di-soersible carbon-nanotube-supported oxide nanoparticles[J].Journal of Physical Chemistry C,2007,111(24):8459.
[22] Xiao-Hong Xia;Zhi-Jie Jia;Ying Yu .Preparation of multi-walled carbon nanotube supported TiO_2 and its photocatalytic activity in the reduction of CO_2 with H_2O[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(4):717-721.
[23] Wenqin Shen;Frank E.Huggins;Naresh Shah .Novel Fe-Ni nanoparticle catalyst for the production of CO-and CO2-free H2 and carbon nanotubes by dehydrogenation of methane[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2008(1):102-110.
[24] Kim B;Sigmund WM .Functionalized multiwall carbon nanotube/gold nanoparticle composites[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(19):8239-8242.
[25] Guo Z P;Han D M;Wexler D et al.Polyoxometallate-sta-bilized platinum catalysts on multi-walled carbon nanotubes for fuel cell applications[J].Electrochimica Acta,2008,53:6410.
[26] Han D M;Guo Z P;Zhao Z W et al.Polyoxomeallate-sta-bilized Pt-Ru catalysts on multiwalled carbon nanotubes:Influence of preparation conditions on the performance of direct methanol fuel cells[J].Journal of Power Sources,2008,184:361.
[27] Roberto Giordano;Philippe Serp;Philippe Kalck;Yolande Kihn;Joachim Schreiber;Christiane Marhic;Jean-Luc Duvail .Preparation of Rhodium Catalysts Supported on Carbon Nanotubes by a Surface Mediated Organometallic Reaction[J].European journal of inorganic chemistry,2003(4):610-617.
[28] Alvaro Carrillo;Jeffrey A. Swartz;Jason M. Gamba;Ravi S. Kane;Nirupama Chakrapani;Bingqing Wei;Pulickel M. Ajayan .Noncovalent Functionalization of Graphite and Carbon Nanotubes with Polymer Multilayers and Gold Nanoparticles[J].Nano letters,2003(10):1437-1440.
[29] Slobodian, P;Pavlinek, V;Lengalova, A;Saha, P .Polystyrene/multi-wall carbon nanotube composites prepared by suspension polymerization and their electrorheological behavior[J].Current applied physics: the official journal of the Korean Physical Society,2009(1):184-188.
[30] Linqin Jiang;Lian Gao;Jing Sun .Production of aqueous colloidal dispersions of carbon nanotubes[J].Journal of Colloid and Interface Science,2003(1):89-94.
[31] Jiang LQ;Gao L .Fabrication and characterization of ZnO-coated multi-walled carbon nanotubes with enhanced photocatalytic activity[J].Materials Chemistry and Physics,2005(2/3):313-316.
[32] Gao B;Peng C;Chen G Z et al.Photo-electro-catalysis enhancement on carbon nanotubes/titanium dioxide (CNTs/ TiO_2) composite prepared by a novel surfactant wrapping sol-gel method[J].Applied Catalysis B:Environmental,2008,85(1-2):17.
[33] Hernadi M.;Couteau E.;Seo JW.;Forro L. .Al(OH)(3)/multiwalled carbon nanotube composite: Homogeneous coverage of Al(OH)(3) on carbon nanotube surfaces[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(17):7026-7029.
[34] Jitianu A;Cacciaguerra T;Berger MH;Benoit R;Beguin F;Bonnamy S .New carbon multiwall nanotubes - TiO2 nanocomposites obtained by the sol-gel method[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2004(0):596-600.
[35] Jing Sun;Lian Gao .Development of a dispersion proces for carbon nanotubes in ceramic matrix by heterocoagulation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(5):1063-1068.
[36] Guo GQ;Qin F;Yang D;Wang CC;Xu HL;Yang S .Synthesis of platinum nanoparticles supported on poly(acrylic acid) grafted MWNTs and their hydrogenation of citral[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(6):2291-2297.
[37] Mu Y Y;Liang H P et al.Controllable Pt nanoparticle deposition on carbon nanotubes as an anode catalyst for direct methanol fuel cell[J].Journal of Physical Chemistry B,2005,109:22212.
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