合成了3,4-二甲氧基苯乙酸邻菲哕啉钆(Ⅲ)配合物:[Gd2(DMPA)6(phen)2](HDMPA=3,4-二甲氧基苯乙酸,C12H12O4;phen=1,10-邻菲哕啉),并通过元素分析、红外光谱、热重分析对其进行了表征,用单晶X射线衍射方法测定了配合物的晶体结构,晶体属于三斜晶系,空间群P-1.测定了铕离子掺杂的配合物的荧光光谱,荧光光谱表明,游离配体没有荧光,在形成配合物后,显示了铕(Ⅲ)离子的特征发射,在591,618,649和684 nm处观察到了4个分别对应于三价铕离子的5S0→7F1,5D0→F2,5D0→F3和5D0→7F4跃迁的特征发射峰,其中以5D0→7F2跃迁的发射最强,这表明配体将吸收的能量有效地转移给了中心离子,配体起到了很好的敏化作用.
参考文献
| [1] | 刘光华.稀土材料学[M].北京:化学工业出版社,2007:1. |
| [2] | Zhou Y F;Hong M C;Wu X T.Lanthanide-transition metal coordination polymers based on multiple N-and O-donor ligands[J].Chemical Communications,2006(135) |
| [3] | Jian-Wen Cheng;Jie Zhang;Shou-Tian Zheng;Man-Bo Zhang;Guo-Yu Yang .Lanthanide-Transition-Metal Sandwich Framework Comprising {Cu3} Cluster Pillars and Layered Networks of {Er36} Wheels[J].Angewandte Chemie,2006(1):73-77. |
| [4] | Figuerola A.;Diaz C.;Ribas J.;Tangoulis V.;Granell J.;Lloret F. Mahia J.;Maestro M. .Synthesis and characterization of heterodinuclear Ln(3+)-Fe3+ and Ln(3+)-Co3+ complexes, bridged by cyanide ligand (Ln(3+) = lanthanide ions). Nature of the magnetic interaction in the Ln(3+)-Fe3+ complexes[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2003(2):641-649. |
| [5] | Liu Q Y;Xu L .Novel structure evolution of lanthanide-SIP coordination polymers(NaH2SIP=5-Sulfoisophthalic acid monosodium salt) from a 1D chain to a 3D network as a consequence of the lanthanide contraction effect[J].European Journal of Inorganic Chemistry,2005,17:3458. |
| [6] | Ma L.;Fowman BM.;Lin WB.;Evans OR. .Luminescent lanthanide coordination polymers[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,1999(25):5837-5840. |
| [7] | Guo D.;Li YT.;Duan CY.;Mo H.;Meng QJ. .Heterodimetallic compounds assembled from ferrocenedicarboxylato and ferrocenecarboxylato ligands[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2003(8):2519-2530. |
| [8] | Pan L.;Adams KM.;Hernandez HE.;Wang XT.;Zheng C.;Hattori Y.;Kaneko K. .Porous lanthanide-organic frameworks: Synthesis, characterization, and unprecedented gas adsorption properties[J].Journal of the American Chemical Society,2003(10):3062-3067. |
| [9] | Ruxandra Gheorghe;Paula Cucos;Marius Andruh;Jean-Pierre Costes;Bruno Donnadieu;Sergiu Shova .Oligonuclear 3d-4f Complexes as Tectons in Designing Supramolecular Solid-State Architectures: Impact of the Nature of Linkers on the Structural Diversity[J].Chemistry: A European journal,2006(1):187-203. |
| [10] | Liu CB;Sun CY;Jin LP;Lu SZ .Supramolecular architecture of new lanthanide coordination polymers of 2-aminoterephthalic acid and 1,10-phenanthroline[J].New Journal of Chemistry,2004(8):1019-1026. |
| [11] | Gao HL;Yi L;Zhao B;Zhao XQ;Cheng P;Liao DZ;Yan SP .Synthesis and characterization of metal-organic frameworks based on 4-hydroxypyridine-2,6-dicarboxylic acid and pyridine-2,6-dicarboxylic acid ligands[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2006(15):5980-5988. |
| [12] | 安保礼,罗一帆,叶剑清,龚孟濂,石建新,麦堪成.稀土配合物Na3Eu（DPA）3掺杂的PMMA树脂的制备及其发光性能[J].中国稀土学报,2001(03):268-271. |
| [13] | 林秦,符连社,梁玉军,郑佑轩,林君,张洪杰.新型稀土芳香羧酸类配合物的合成及其光致和电致发光性质[J].中国稀土学报,2003(01):19-22. |
| [14] | Frederick S R .Terbium (Ⅲ) and europium (Ⅲ) ions as luminescent probes and stains for biomolecular systems[J].Chemical Reviews,1982,82(05):541. |
| [15] | Scheldrick G M.SADABS[M].G(o)ttingen University,Germany,1996 |
| [16] | Sheldrick G M.SHELXS97,Program for the Solution of Crystal Structure[M].University of Gottingen,Germay,1997 |
| [17] | Sheldrick G M.SHELXS 97.Program for the Refinement of Crystal Structure[M].University of Gottingen,Germay,1997 |
| [18] | Udai P S;Shalu T;Chokhe L S;Helmut G,Thomas W.Synthesis,molecular structure and emission properties of benzoatebridged lanthanide complexes with hydrotris (pyrazolyl) borate[J].Journal of the Chemical Society,Dalton Transactions,2002(4464) |
| [19] | 李夏;杨永丽;王繁泓 .钕与3-甲氧基苯甲酸和邻菲罗琳三元配合物的合成及光谱表征[J].光谱学与光谱分析,1998,18(02):234. |
| [20] | Rizzi A.;Baggio R.;Garland MT.;Pena O.;Perec M. .New homobinuclear carboxylate-bridged gadolinium(III) complexes[J].Inorganica Chimica Acta,2003(0):315-319. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%