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藉由分析觸媒及奈米綫之結構與組成,詳細探討合成氧化矽奈米綫的固-液-固成長機制.與一般化學汽相沉積法不同的是,矽的來源直接由矽基板提供固態矽源.首先在矽基板上濺鍍上一層很薄(~5nm)的白金觸媒層.在升温過程中,白金薄膜會分裂形成直徑爲數百奈米大小的觸媒球.掃描式電子顯微鏡及穿透式電子顯微鏡的分析結果顯示,這些觸媒球的組成爲Pt3Si,并可作爲奈米綫成長的孕核點.在高達1100℃C的制程温度及5h的持温之下,矽基板氧化成爲氧化矽并藉由擴散溶解到觸媒球中,直到館和點而后析出成爲氧化矽的奈米綫.這些奈米綫爲非晶結構,直徑爲40~60nm,長度爲數百微米.

参考文献

[1] Morles A M;Lieber W C .[J].Science,1998,279:208.
[2] Zhang YF.;Wang N.;Yu DP.;Lee CS.;Bello I.;Lee ST.;Tang YH. .Silicon nanowires prepared by laser ablation at high temperature[J].Applied physics letters,1998(15):1835-1837.
[3] Westwater J.;Tomiya S.;Usui S.;Ruda H.;Gosain DP. .GROWTH OF SILICON NANOWIRES VIA GOLD/SILANE VAPOR-LIQUID-SOLID REACTION[J].Journal of Vacuum Science & Technology, B. Microelectronics and Nanometer Structures: Processing, Measurement and Phenomena,1997(3):554-557.
[4] Ozaki N.;Takeda S.;Ohno Y. .Silicon nanowhiskers grown on a hydrogen-terminated silicon {111} surface[J].Applied physics letters,1998(25):3700-3702.
[5] Liu H;Biegelsen D K;Johnson N M et al.[J].Journal of Vacuum Science and Technology B:Microelectronics and Nanometer Structures,1995,13:2166.
[6] Liu H;Biegelsen D K;Johnson N M.[J].Applied Physics Letters,1994(64):1385.
[7] Zhan Y G;Wang N L;He R R et al.[J].Journal of Crystal Growth,2001,233:803.
[8] Zhang Y F;Tang Y H;Wang N et al.[J].Journal of Crystal Growth,1999,197:136.
[9] Yu DP.;Hang QL.;Yan HF.;Xu J.;Xi ZH.;Feng SQ.;Xing YJ. .Controlled growth of oriented amorphous silicon nanowires via a solid-liquid-solid (SLS) mechanism[J].Physica, E. Low-dimensional systems & nanostructures,2001(2):305-309.
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