报道了UO2+x芯块低温烧结实验的结果.12组芯块在N2+CO2组成的部分氧化气氛下于立式钼丝炉中低温烧结.UO2芯块要获得密度为10.41g/cm3(94.98%理论密度)需在氢气氛中于2073~2273K下烧结,而UO2+x芯块实现该密度的烧结温度可降低400K以上.建立了超氧化铀缺陷模型来研究低温烧结的活化机理.研究发现铀离子扩散系数与气氛中氧分压或是UO2+x中x成正比.利用铀离子的扩散系数,可预测UO2+x芯块在1073、1273、1473和1673K温度下的烧结密度;还可算出x=0.04时,UO2+x芯块在部分氧化气氛下的理论烧成温度.计算所得烧结密度和烧成温度与实验结果符合得很好.
参考文献
[1] | 杨晓东,高家诚,伍志明,王勇.二氧化铀芯块的低分压氧化性气氛烧结[J].原子能科学技术,2006(06):682-687. |
[2] | Lahiri D;Rao SVR;Rao GVSH;Srivastava RK .Study on sintering kinetics and activation energy of UO2 pellets using three different methods[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2006(1/3):88-96. |
[3] | Kutty TRG;Khan KB;Kutty PS;Basak CB;Sengupta AK;Mehrotra RS;Majumdar S;Kamath HS .Densification behaviour and sintering kinetics of (U0.45Pu0.55)C pellets[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2005(1):113-118. |
[4] | Ruello P.;Chirlesan G.;Petot-Ervas G.;Petot C.;Desgranges L. .Chemical diffusion in uranium dioxide - influence of defect interactions[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2004(2/3):202-209. |
[5] | Dehaudt P;Bourgeois L;Chevrel H .Activation energy of UO2 and UO2+x sintering[J].Journal of Nuclear Materials,2001,299(03):250-259. |
[6] | Balakrishna P.;Chakraborthy KP.;Jayaraj RN.;Ganguly C.;Murty BN. .Coarsening-densification transition temperature in sintering of uranium dioxide[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2001(1):35-42. |
[7] | Chevrel H;Dehaudt P;Francois B et al.Influence of surface phenomena during sintering of overstoichiometric uranium dioxide UO2+x[J].Journal of Nuclear Materials,1992,189(02):175-182. |
[8] | Song K W;Kim S H;Na S H et al.Effects of Nb2O5 addition on grain growth and densification in UO2 pellets under reducing and/or oxidizing atmospheres[J].Journal of Nuclear Materials,1994,209(03):280-285. |
[9] | Ayaz B.;Bilge AN. .The possible usage of ex-ADU uranium dioxide fuel pellets with low-temperature sintering[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2000(1):45-50. |
[10] | Harada Y. .UO2 SINTERING IN CONTROLLED OXYGEN ATMOSPHERES OF THREE-STAGE PROCESS[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,1997(2/3):217-223. |
[11] | 高家诚,李锐,钟凤伟,杨晓东,王勇.二氧化铀陶瓷燃料块工艺研究进展[J].功能材料,2006(06):849-852. |
[12] | YANG Xiao-dong,GAO Jia-cheng,WANG Yong,CHANG Xin.Low-temperature sintering process for UO2 pellets in partially-oxidative atmosphere[J].中国有色金属学会会刊(英文版),2008(01):171-177. |
[13] | Frost B R T.Nuclear Materials Part Ⅰ[M].北京:科学出版社,1999:140. |
[14] | Li R .Study on mechanics of low-temperature sintering of UO2 pellets[D].重庆:重庆大学,2006. |
[15] | Gao JH;Yang XD;Li R;Wang Y;Zhong FW .Low-temperature sintering mechanism on uranium dioxide[J].Journal of Materials Science,2007(15):5936-5940. |
[16] | Kingery W D;Berg M .Study of the initial stages of sintering solids by viscous flow,evaporation-condensation and self-diffusion[J].Journal of Applied Physics,1955,26(10):1205-1212. |
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