介绍了影响锂硫电池实用化的瓶颈问题,如硫利用率低、不可逆Li2S形成、硫正极结构不稳定等；综述了性能改善方案,如硫正极改性、S/C复合、合适的粘结剂、胶体电解质及锂负极保护等；最后提出了今后重点研究的方向.
参考文献
| [1] | 王维坤,余仲宝,苑克国,王安邦,杨裕生.高比能锂硫电池关键材料的研究[J].化学进展,2011(02):540-547. |
| [2] | 熊仕昭;洪晓斌 等.改善锂硫电池循环性能研究进展[J].化学进展,2011,30(05):991. |
| [3] | Marmorstein D;Yu T H;Striebel K A et al.Electrochemical performance of lithium/sulfur cells with three different polymer electrolytes[J].Journal of Power Sources,2000,89(02):219. |
| [4] | 余仲宝,王维坤,王安邦,杨裕生.软包装Li/S电池的性能研究[J].电池,2007(04):247-249. |
| [5] | Xiangming He;Weihua Pu;Jianguo Ren;Li Wang;Jiulin Wang;Changyin Jiang;Chunrong Wan .Charge/discharge characteristics of sulfur composite cathode materials in rechargeable lithium batteries[J].Electrochimica Acta,2007(25):7362-7371. |
| [6] | 苑克国,王安邦,余仲宝,王维坤,杨裕生.1,3-二氧戊环基LiCF3SO3电解液对锂硫电池正极材料单质硫的电化学性能影响[J].高等学校化学学报,2006(09):1738-1741. |
| [7] | Ran Elazari;Gregory Salitra;Yossi Talyosef;Judith Grinblat;Charislea Scordilis-Kelley;Ang Xiao;John Affinito;Doron Aurbach .Morphological and Structural Studies of Composite Sulfur Electrodes upon Cycling by HRTEM, AFM and Raman Spectroscopy[J].Journal of the Electrochemical Society,2010(10):A1131-A1138. |
| [8] | Young-Jin Choi;Young-Dong Chung;Chang-Yong Baek;Ki-Won Kim;Hyo-Jun Ahn;Jou-Hyeon Ahn .Effects Of Carbon Coating On The Electrochemical Properties Of Sulfur Cathode For Lithium/sulfur Cell[J].Journal of Power Sources,2008(2):548-552. |
| [9] | Lixia Yuan;Huiping Yuan;Xinping Qiu;Liquan Chen;Wentao Zhu .Improvement Of Cycle Property Of Sulfur-coated Multi-walled Carbon Nanotubes Composite Cathode For Lithium/sulfur Batteries[J].Journal of Power Sources,2009(2):1141-1146. |
| [10] | 马萍,徐宇虹,张宝宏,殷金玲,孟祥利.Li/S电池凝胶聚合物电解质的研究[J].电池,2006(06):426-428. |
| [11] | Jing Sun;Yaqin Huang;Weikun Wang;Zhongbao Yu;Anbang Wang;Keguo Yuan .Application of gelatin as a binder for the sulfur cathode in lithium-sulfur batteries[J].Electrochimica Acta,2008(24):7084-7088. |
| [12] | Naoi K;Kawase K I;Inoue Y .A new energy storage material:Organosulfur compounds based on multiple sulfur sulfur bonds[J].Journal of the Electrochemical Society,1997,144(06):L170. |
| [13] | 徐国祥,其鲁,闻雷,陈永翀,晨晖,慈云祥.新型正极材料三硫代环磷氮烯无机聚合物的合成[J].无机化学学报,2005(11):1609-1613. |
| [14] | Naoi K;Kawase K I;Mori M et al.Electrochemistry of poly(2,2-dithiodianiline):A new class of high energy conducting polymer interconnected with S-S bonds[J].Journal of the Electrochemical Society,1997,144(06):L173. |
| [15] | 辛森,郭玉国,万立骏.高能量密度锂二次电池电极材料研究进展[J].中国科学（化学）,2011(08):1229-1239. |
| [16] | Akitoshi Hayashi;Takamasa Ohtomo;Fuminori Mizuno;Kiyoharu Tadanaga;Masahiro Tatsumisago .All-solid-state Li/S batteries with highly conductive glass-ceramic electrolytes[J].Electrochemistry communications,2003(8):701-705. |
| [17] | 马萍,张宝宏,巩桂英,徐宇虹.V2O5（TiO2）/S复合材料作锂电池正极的性能研究[J].电子元件与材料,2007(08):42-45. |
| [18] | Min-Sang Song;Sang-Cheol Han;Hyun-Seok Kim .Effects of Nanosized Adsorbing Material on Electrochemical Properties of Sulfur Cathodes for Li/S Secondary Batteries[J].Journal of the Electrochemical Society,2004(6):A791-A795. |
| [19] | 熊仕昭,王华林,洪晓斌,谢凯,周勇军.聚苯胺包覆对锂硫电池电化学性能的影响[J].电源技术,2011(06):678-680. |
| [20] | Wang J L;Yang Y;Xie J Y et al.A novel conductive polymer/sulfur composite cathode material for rechargeable lithium batteries[J].Advanced Materials,2002,14(13):991. |
| [21] | J. Wang;J. Chen;K. Konstantinov;L. Zhao;S. H. Ng;G. X. Wang;Z. P. Guo;H. K. Liu .Sulphur-polypyrrole composite positive electrode materials for rechargeable lithium batteries[J].Electrochimica Acta,2006(22):4634-4638. |
| [22] | Xiulei Ji;Kyu Tae Lee;Linda F. Nazar .A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries[J].Nature Materials,2009(6):500-506. |
| [23] | Liang C D;Dudney N J;Howe J Y .Hierarchically structured sulfur/carbon nanocomposited material for high-energy Lithium battery[J].Chemistry of Materials,2009,21(19):4724. |
| [24] | W. Zheng;Y. W. Liu;X. G. Hu;C. F. Zhang .Novel nanosized adsorbing sulfur composite cathode materials for the advanced secondary lithium batteries[J].Electrochimica Acta,2006(7):1330-1335. |
| [25] | 吴锋,吴生先,陈人杰,陈实,王国庆.多壁碳纳米管对单质硫正极材料电化学性能的改性[J].新型炭材料,2010(06):421-425. |
| [26] | Wook Ahn;Kwang-Bum Kim;Kyu-Nam Jung;Kyoung-Hee Shin;Chang-Soojin .Synthesis and electrochemical properties of a sulfur-multi walled carbon nanotubes composite as a cathode material for lithium sulfur batteries[J].Journal of Power Sources,2012(Mar.15):394-399. |
| [27] | Zhang B;Lai C;Zhou Z et al.Preparation and electrochemical properties of sulfur-acetylene black composites as cathode materials[J].Electrochimica Acta,2009,54:3708. |
| [28] | Rao Mumin;Song Xiangyun et al.Carbon nanofiber-sulfur composite cathode materials with different binders for secondary Li/S cells[J].Electrochimica Acta,2012,65:228. |
| [29] | Sun J;Huang YQ;Wang WK;Yu ZB;Wang AB;Yuan KG .Preparation and electrochemical characterization of the porous sulfur cathode using a gelatin binder[J].Electrochemistry communications,2008(6):930-933. |
| [30] | 伍英蕾,杨军,王久林,尹利超,努丽燕娜.高性能锂-硫电池用复合正极的构造与粘结剂[J].物理化学学报,2010(02):283-290. |
| [31] | Holger Schneider;Arnd Garsuch;Alexander Panchenko;Oliver Gronwald;Nicole Janssen;Petr Novak .Influence of different electrode compositions and binder materials on the performance of lithium-sulfur batteries[J].Journal of Power Sources,2012(May 1):420-425. |
| [32] | Saikia D;Kumar A .Ionic conduction studies in P(VDF-HFP)-LiAsF6-(PC + DEC)-fumed SiO2 composite gel polymer electrolyte system[J].Physica Status Solidi, A. Applied Research,2005(2):309-315. |
| [33] | 李为立 .锂离子电池用凝胶聚合物电解质的设计、制备与表征[D].浙江大学,2007. |
| [34] | Yu X;Xie J;Yang J et al.All solid state rechargeable lithium cells based on nano sulfur composite cat-hodes[J].Journal of Power Sources,2004,132(1-2):181. |
| [35] | Skotheim T A .Lithium anodes for electrochemical cells[P].US,7247408,2007-07-24. |
| [36] | Affinito J D .Methods and apparatus for vacuum thin film deposition[P].US,7112351,2006-09-26. |
| [37] | Mikhaylik Y V .Electrolytes for lithium sulfur cells[P].US,20050147891,2005-07-07. |
| [38] | Jae-Won Choi;Gouri Cheruvally;Dul-Sun Kim;Jou-Hyeon Ahn;Ki-Won Kim;Hyo-Jun Ahn .Rechargeable Lithium/sulfur Battery With Liquid Electrolytes Containing Toluene As Additive[J].Journal of Power Sources,2008(1):441-445. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%