以二价和三价铁为铁源,乙二醇为络合剂及碳源,水为溶剂,采用溶胶-凝胶一步烧结法制备LiFePO4/C正极材料.采用X射线衍射仪、扫描电子显微镜和元素分析仪等分别对样品的相结构、形貌和碳含量进行表征.研究电极在不同放电倍率下的充放电特性,采用电化学交流阻抗谱和循环伏安法研究LiFePO4/C电极反应的动力学性能.结果表明:以水为溶剂,采用三价铁源获得产物中未发现除LiFePO4以外的相,而采用二价铁源制备的产物中除LiFePO4主相外还存在微量的FeP相;微量FeP相的存在提高LiFePO4/C的综合电化学性能;以二价铁源制备的LiFePO4/C在0.1C和1C(1C=170 mA/g,2.5~4.2 V)下的放电比容量分别为142和112 mA·h/g,高于采用三价铁源制备的LiFePO4/C.
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