采用激活能测试装置测量VHF-PECVD高速沉积的本征微晶硅薄膜,并对不同晶化率的样品和不同沉积功率、不同沉积压强条件下沉积制备的样品的激活能进行了分析研究.结果表明:在非晶-微晶相变域附近,激活能随着晶化率的升高而降低;随着沉积功率的增大和沉积气压的增大,沉积速率提高,样品的激活能升高,通过提高沉积功率和沉积气压可以有效的抑制氧污染.
Intrinsic microcrystalline silicon thin films were deposited by VHF PECVD, the activation energy of thin films were measured by activation energy testing equipment. The activation energy of samples with different crystalline volume fractions prepared at different power and different pressure were studied. The results showed that the activation energy of samples deposited at amorphous/microcrystalline transition zone decreased as the crystalline volume fractions increasing. As the depositing power and pressure increasing, the depositing rates and activation energy were also increased. As a result, oxygen contamination could be suppressed by increasing depositing rates using relatively higher power and pressure.
参考文献
[1] | Yan B J;Yue G Z;Yang J et al.Hydrogenated Microcrystalline Silicon Single-junction and Multi-junction Solar Cells[J].Materials Research Society,2003,762:309-320. |
[2] | Kenji Yamamoto;Akihiko Nakajima;Masashi Yoshimi;Toru Sawada;Susumu Fukuda;Takashi Suezaki;Mitsuru Ichikawa;Yohei Koi;Masahiro Goto;Tomomi Meguro;Takahiro Matsuda;Masataka Kondo;Toshiaki Sasaki;Yuko Tawada .A high efficiency thin film silicon solar cell and module[J].Solar Energy,2004(6):939-949. |
[3] | Klein S;Repmann T;Brammer T et al.Microsrystalline Silicon(μc-Si:H) Films and Solar Cells Deposited by PECVD and HWCVD[J].Journal of Solar Energy Engineering,2004,77(06):893-908. |
[4] | van Veen MK.;van der Werf CHM.;Rath JK.;Schropp REI. .Incorporation of amorphous and microcrystalline silicon in n-i-p solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(1/2):216-219. |
[5] | Shah A.;Torres P.;Meier J.;Kroll U.;Hof C.;Droz C. Goerlitzer M.;Wyrsch N.;Vanecek M.;Vallat-Sauvain E. .Intrinsic microcrystalline silicon (mu c-Si : H) deposited by VHF-GD (very high frequency-glow discharge): a new material for photovoltaics and optoelectronics[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2000(0):219-226. |
[6] | Prasad K;Finger F;Dubail S et al.Deposition of Phosphorus Doped Microcrystalline Silicon below 170 ℃ at 70 MHz[J].Non-Crystalline Solids,1991,137/138:681. |
[7] | Kirkpatrick S .Percolation and Conduction[J].Reviews of Modern Physics,1973,45(04):574-588. |
[8] | Shah A.;Meier J.;Vallat-Sauvain E.;Droz C.;Kroll U.;Wyrsch N. Guillet J.;Graf U. .Microcrystalline silicon and 'micromorph' tandem solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(0):179-187. |
[9] | Schropp REI.;Rath JK.;Alkemade PFA. .Poly-silicon films with low impurity concentration made by hot wire chemical vapour deposition[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1/4):541-547. |
[10] | 张晓丹,赵颖,朱锋,魏长春,麦耀华,高艳涛,孙建,耿新华,熊绍珍.二次离子质谱深度剖面分析氢化微晶硅薄膜中的氧污染[J].物理学报,2005(04):1895-1898. |
[11] | 杨恢东,吴春亚,赵颖,薛俊明,耿新华,熊绍珍.甚高频等离子体增强化学气相沉积法沉积μc-Si∶H薄膜中氧污染的初步研究[J].物理学报,2003(11):2865-2869. |
[12] | 张晓丹,赵颖,朱锋,魏长春,高艳涛,孙建,侯国付,薛俊明,张德坤,任慧志,耿新华,熊绍珍.纯化器对VHF-PECVD制备的不同结构硅薄膜特性的影响[J].人工晶体学报,2004(06):892-897. |
[13] | 黄君凯,杨恢东.弱硼掺杂补偿对氢化微晶硅薄膜制备与特性的影响[J].半导体学报,2005(06):1164-1168. |
[14] | 张晓丹,朱锋,赵颖,侯国付,魏长春,孙建,张德坤,任慧志,薛俊明,耿新华,熊绍珍.气压对VHF-PECVD制备的μc-Si:H 薄膜特性影响的研究[J].人工晶体学报,2004(03):414-418. |
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