水热法合成了1个新的锌配位聚合物[Zn(trans-chdc)(bbmb)]n(H2trans-chdc=反-1,4-环己二酸；bbmb=4,4'-二(苯并咪唑-1-甲基)联苯),并通过红外光谱、元素分析、XRD、TGA和X射线单晶衍射对配合物的单晶结构进行了表征.该配合物属正交晶系,Pbcm空间群,晶胞参数为a=0.5731 (2)nm,b=1.9891(8) nm,c=2.7688(12) nm,V=3.157(2) nm3,Z=4.晶体结构分析表明该配合物为具有四重穿插金刚石拓扑的三维结构.室温固态荧光测试显示,配合物在533 nm(λmax)具有强的荧光吸收.
参考文献
| [1] | Yue-Biao Zhang;Wei-Xiong Zhang;Fei-Yue Feng .A Highly Connected Porous Coordination Polymer with Unusual Channel Structure and Sorption Properties[J].Angewandte Chemie,2009(29):5287-5290. |
| [2] | Qi ZP;Bai ZS;Yuan Q;Okamura T;Cai K;Su Z;Sun WY;Ueyama N .pH-dependent self-assembly of copper(II) complexes with a new imidazole-containing polyamine ligand: Synthesis, structure and magnetic property[J].Polyhedron: The International Journal for Inorganic and Organometallic Chemistry,2008(12):2672-2680. |
| [3] | 于连香,马奎蓉,范勇,张萍.水热合成三维超分子配位聚合物[Cd（C2O4）（H2O）2]·H2O及晶体结构[J].人工晶体学报,2007(01):146-151. |
| [4] | Qin, L.;Hu, J.-S.;Huang, L.-F.;Li, Y.-Z.;Guo, Z.-J.;Zheng, H.-G. .Syntheses, characterizations, and properties of six metal-organic complexes based on flexible ligand 5-(4-pyridyl)-methoxyl isophthalic acid[J].Crystal growth & design,2010(9):4176-4183. |
| [5] | 秦秀英,李光照,张淑华,刘峥.Ni（Ⅱ）-3,5-二氯水杨醛缩氨基甲磺酸席夫碱-邻菲咯林三元配合物的合成及晶体结构[J].人工晶体学报,2008(06):1448-1452. |
| [6] | 胡喜兰,施鹏飞,许兴友,尹福军,王大奇.配合物[Cu（abpa）（pht）] pht·CH3OH的合成、晶体结构和抗微生物活性[J].人工晶体学报,2009(03):797-802. |
| [7] | 韩银锋,刘涛,段文增,吴仁涛,李季坤,李小燕.偶氮二苯甲酸及联吡啶构筑的三重穿插钴配位聚合物的溶剂热合成、结构和热稳定性研究[J].无机化学学报,2012(01):149-152. |
| [8] | Dobrzanska L;Lloyd GO;Jacobs T;Rootman I;Oliver CL;Bredenkamp MW;Barbour LJ .Construction of one- and two-dimensional coordination polymers using ditopic imidazole ligands[J].Journal of Molecular Structure,2006(1/3):107-113. |
| [9] | Yang EC;Zhao HK;Ding B;Wang XG;Zhao XJ .Four novel three-dimensional triazole-based zinc(II) metal-organic frameworks controlled by the spacers of dicarboxylate ligands: Hydrothermal synthesis, crystal structure, and luminescence properties[J].Crystal growth & design,2007(10):2009-2015. |
| [10] | Wang ZW;Ji CC;Li J;Guo ZJ;Li YZ;Zheng HG .Synthesis, X-ray Structures, and Fluorescent Properties of Coordination Networks Constructed from 2-(2-Pyridinyl-benzimidazolyl) Acetic Anion[J].Crystal growth & design,2009(1):475-482. |
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