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为了解天津钢管集团公司EAFLF/VDCC工艺生产压力容器钢12Cr1MoVG的洁净度水平,通过系统取样、示踪剂追踪、综合分析等方法,对LF处理前后、中间包钢水和连铸坯中总氧、显微夹杂及大型夹杂物的数量及变化情况进行了全面研究。结果表明,LF/VD精炼后钢液w(T[O])平均为15×10-6,中间包为17×10-6,铸坯为(18~24)×10-6,其中头坯>尾坯>连浇坯>正常坯。铸坯中的显微夹杂物数量是3.53个/mm2,主要为球形钙铝酸盐、硅铝酸盐和铝酸盐与硫化物的复合夹杂,90%以上的夹杂物尺寸小于10 μm;铸坯中大型夹杂物有铁铝硅酸盐、钙镁硅酸盐等,来源于钢的二次氧化、钢包卷渣、耐火材料侵蚀、结晶器卷渣等。

In order to study the cleanliness of pressure vessel steel 12Cr1MoVG produced by EAFLF/VDCC route at Tianjin Pipe Company Ltd., the change of total oxygen (w(T[O])), microinclusion and macroinclusion content in the liquid steel through the process was measured systematically,with tracers and comprehensive analysis of samples. The results showed that in experimental heats the w(T[O]) was 15×10-6 after LF/VD refining and 17×10-6 in tundish, and (1824)×10-6 in billet in average. The number of microinclusions less than 10 μm in size was 353/mm2, which were mainly spherical calcium aluminate, aluminosilicate and compound inclusion of aluminate and sulphide. The macroinclusions were mainly ferrumaluminum silicate, magnesiumcalcium silicate, et al, which are formed during reoxidation, refractory erosion and slag entrainment in ladle and mold.

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