利用芘丁醇和8-壬烯酸的酯化反应,合成了含长链烷基的芘类衍生物8-壬烯酸芘丁酯,用红外光谱(IR)和核磁共振(1HMR)表征其分子结构,研究了它在甲苯和硅树脂中的荧光特性和热稳定性,考察了不同芘类衍生物对光学压敏涂料热稳定性的影响.结果表明,合成的舍长链烷基的芘类衍生物8-壬烯酸芘丁酯在溶液及涂料中都具有较高的氧猝灭率,随着芘类衍生物链长的增长,荧光分子在溶液及涂料中的氧猝灭率略有减小,而在涂料中的热稳定性有较大的提高.
参考文献
[1] | Biniam Zelelow;Gamal E. Khalil;Greg Phelan;Brenden Carlson;Martin Gouterman;James B. Callis;Larry R. Dalton .Dual luminophor pressure sensitive paint Ⅱ. Lifetime based measurement of pressure and temperature[J].Sensors and Actuators, B. Chemical,2003(1/2):304-314. |
[2] | Sami Alaruri;Tom Bonsett;Donald Smith .An endoscopic imaging system for turbine engine pressure sensitive paint measurements[J].Optics and Lasers in Engineering,2001(3):277-287. |
[3] | Christian Klein .Application of Pressure Sensitive Paint (PSP) for the determination of the instantaneous pressure field of models in a wind tunnel[J].Aerospace science and technology,2000(2):103-109. |
[4] | 晏华,王雪梅,余荣升,张斌,陈淑莲.含长链烷基芘类衍生物的合成与氧猝灭特性[J].功能材料,2007(05):795-797,801. |
[5] | 蒋峰芝,许认,王夺元,董兴德,李桂春.气动力压敏漆发光氧猝灭影响因素的研究[J].功能材料,2000(01):72-76. |
[6] | 肖亚克,马洪志,张孝棣,贾元胜.光学压力敏感涂料的研制[J].传感器技术,2003(04):29-32. |
[7] | Bharathibai J. Basu;K.S. Rajam .Comparison of the oxygen sensor performance of some pyrene derivatives in silicone polymer matrix[J].Sensors and Actuators, B. Chemical,2004(2/3):459-467. |
[8] | Basu, BJ;Vasantharajan, N;Raju, C .A novel pyrene-based binary pressure sensitive paint with low temperature coefficient and improved stability[J].Sensors and Actuators, B. Chemical,2009(1):283-288. |
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