简要介绍了瓜环化学的概念、定义、结构特征及应用新进展。重点综述了:①新型瓜环超分子聚合物的自组装合成;②新型瓜环化合物在轻重稀土分离中的应用研究;③新型瓜环化合物与碱土金属管状配位聚合物的合成研究。并对瓜环化学的发展进行了展望。
The concepts,definitions,structure features,and applications of cucurbituril chemistry were introduced briefly in this paper. Emphases are put on from three parts:①Self-assembly synthesis of new cucurbituril supramo-lecular polymers;②applications of new cucurbituril compounds to metal separations;③tubular coordination polymers synthesis of new cucurbituril compounds and alkaline earth metals. Future developments are prospected in the end.
参考文献
[1] | Buschmann H J;Jansen K;Schollmeyer E .Cucur-bit [6] uril as ligand for the complexation of lan-thanide cations in aqueous solution[J].Inorganic Chemistry Communications,2003,6(05):531-534. |
[2] | Klock, C;Dsouza, RN;Nau, WM .Cucurbituril-Mediated Supramolecular Acid Catalysis[J].Organic letters,2009(12):2595-2598. |
[3] | 杨波;吴明强;肖昕.七元瓜环与N,N′-二甲基-苯甲基-1,10-二氨基癸烷的超分子自组装[A].吉林延吉:延边大学,2014:150-151. |
[4] | 陈鹏;肖勃;高瑞晗.一种六元瓜环桥联丙烯酸聚合物的制备方法[A].吉林延吉:延边大学,2014:153-154. |
[5] | 陈任焰;倪新龙;陶朱.七元瓜环与4,4-联吡啶类长链轴线分子的主客体自组装研究[A].吉林延吉:延边大学,2014:162-163. |
[6] | 王传增;赵文暄;张云黔.单取代六元瓜环对轻重稀土分离的研究[A].吉林延吉:延边大学,2014:142-143. |
[7] | 尉鑫;张云黔;薛赛风.对称八甲基六元瓜环-稀土加合物的应用研究[A].吉林延吉:延边大学,2014:146-147. |
[8] | 尉鑫;赵迎春;肖昕.邻位四甲基六元瓜环-稀土加合物的应用研究[A].吉林延吉:延边大学,2014:144-145. |
[9] | 周加加;尉鑫;赵迎春.邻位四甲基六元瓜环与碱土金属管状配位聚合物研究[A].吉林延吉:延边大学,2014:148-149. |
[10] | 赵文暄;王传增;张云黔.HHQ [6]与碱土金属管状配位聚合物形成[A].吉林延吉:延边大学,2014:141-142. |
[11] | Xiao X;Tao Z;Zhang Y Q .Coordination poly-mers constructed from alkali metal ions and(HO)10 Cucurbit[5] uril[J].Cryst Eng comm,2011,13:3794-3800. |
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