欢迎登录材料期刊网

材料期刊网

高级检索

Nafion(R) 等全氟磺酸膜由于寿命长,导电性能优越,长久以来一直应用于质子交换膜燃料电池中,但其价格昂贵,甲醇阻隔性能差,工作温度高于100℃后,导电性随着水的挥发流失而迅速下降.而解决燃料电池中催化剂一氧化碳中毒和提高燃料转化效率的有效办法是提高工作温度.能在中高温环境中工作的质子导电材料已成为研究热点之一.综述了近年来应用于中温质子交换膜燃料电池中质子导电膜的研究进展,并评述了非水体系和高温水汽体系.

参考文献

[1] Kim YS.;Wang F.;Hickner M.;McCartney S.;Hong YT.;Harrison W. Zawodzinski TA.;McGrath JE. .Effect of acidification treatment and morphological stability of sulfonated poly(arylene ether sulfone) copolymer proton-exchange membranes for fuel-cell use above 100 degrees C[J].Journal of Polymer Science, Part B. Polymer Physics,2003(22):2816-2828.
[2] LaminieJ;Dicks A.Fuel Cell System Explained[J].Wiley England,2000
[3] IannielloR;Schmidt V M;Stimming U et al.[J].Electrochimica Acta,1994,39:1863.
[4] AlertiG;Casciola M et al.[J].Journal of Membrane Science,2001,185:73.
[5] AlertiG;Casciola M et al.[J].Journal of Membrane Science,2000,172:233.
[6] Wang JT.;Weber M.;Wasmus S.;Savinell RF.;Lin WF. .Trimethoxymethane as an alternative fuel for a direct oxidation PBI polymer electrolyte fuel cell[J].Electrochimica Acta,1998(24):3821-3828.
[7] ozkurtA et al.[J].Solid State Ionics,1999,125:225.
[8] Schuster M.;Wegner G.;Herz HG.;Ise M.;Kreuer KD.;Maier J.;Meyer WH. .Proton mobility in oligomer-bound proton solvents: imidazole immobilization via flexible spacers[J].Solid state ionics,2001(1/4):85-92.
[9] PerssonJC;Jannasch P .[J].Chemistry of Materials,2003,15:3044.
[10] PuHT .[J].Polymer International,2003,52:1540.
[11] HanMG;Im S S .[J].Journal of Applied Polymer Science,1998,67:1836.
[12] Kreuer KD.;Ise M.;Spaeth M.;Maier J.;Fuchs A. .Imidazole and pyrazole-based proton conducting polymers and liquids[J].Electrochimica Acta,1998(10/11):1281-1288.
[13] Schechter A.;Savinell RF. .Imidazole and 1-methyl imidazole in phosphoric acid doped polybenzimidazole, electrolyte for fuel cells[J].Solid state ionics,2002(1/2):181-187.
[14] YamadaM;Honma I .[J].Electrochimica Acta,2003,48:2411.
[15] 黄时中;张昌莘;严祖同 .[J].安徽师范大学学报(自然科学版),1997,20(02):164.
[16] HonmaI;Nakajima H;Nomura S .[J].Solid State Ionics,2002,154-155:707.
[17] HonmaI et al.[J].Solid State Ionics,1999,120:255.
[18] Honma I.;Nakajima H.;Nishikawa O.;Sugimoto T.;Nomura S. .Organic/inorganic nano-composites for high temperature proton conducting polymer electrolytes[J].Solid state ionics,2003(special issue si):237-245.
[19] Nakajima H.;Honma I. .Proton-conducting hybrid solid electrolytes for intermediate temperature fuel cells[J].Solid state ionics,2002(3/4):607-610.
[20] Tadanaga K.;Yoshida H.;Matsuda A.;Minami T.;Tatsumisago M. .Preparation of proton-conductive inorganic-organic hybrid films from 3-glycidoxypropyltrimethoxysilane and orthophosphoric acid[J].Chemistry of Materials,2003(9):1910-1912.
[21] StaitiP;Minutoli M et al.[J].Journal of Power Sources,2000,90:231.
[22] Xing;Savadogo O .[J].Journal of New Materials for Electrochemical Systems,1999,2:95.
[23] StaitiP .[J].Materials Letters,2001,47:241.
[24] StaitiP;Minutoli M J .[J].Journal of Power Sources,2001,94:9.
[25] oysenDA;Chrisholm C R I;Haile S M et al.[J].Journal of the Electrochemical Society,2000,147:3610.
[26] PoltarzewskiZ;Wieczorek W;Przyluski J et al.[J].Solid State Ionics,1999,119:301.
[27] Park YI.;Nagai M.;Kim JD. .High proton conductivity in ZrP-PTFE composites[J].Journal of Materials Science Letters,2000(19):1735-1738.
[28] AlertiG;Casciola M;Massinelli L et al.[J].Journal of Membrane Science,2001,185:73.
[29] Wang F.;Hickner M.;Kim YS.;Zawodzinski TA.;McGrath JE. .Direct polymerization of sulfonated poly(arylene ether sulfone) random (statistical) copolymers: candidates for new proton exchange membranes[J].Journal of Membrane Science,2002(1/2):231-242.
[30] Poppe D.;Frey H.;Kreuer KD.;Heinzel A.;Mulhaupt R. .Carboxylated and sulfonated poly(arylene-co-arylene sulfone)s: Thermostable polyelectrolytes for fuel cell applications[J].Macromolecules,2002(21):7936-7941.
[31] JonissenL;Gogel V;Kerres J et al.[J].Journal of Power Sources,2002,105:267.
[32] KawaharaM;Rikukawa M;Sanui K .[J].Polymers For Advanced Technologies,2000,11:544.
[33] AsensioJA et al.[J].Journal of Polymer Science,2002,40:3703.
[34] aeJM et al.[J].Solid State Ionics,2002,147:189.
[35] StaitiP;Lufrano F et al.[J].Journal of Membrane Science,2001,188:71.
[36] Hara S.;Sakamoto H.;Miyayama M.;Kudo T. .Proton-conducting properties of hydrated tin dioxide as an electrolyte for fuel cells at intermediate temperature[J].Solid state ionics,2002(Pt.B):679-685.
[37] EnglandWA;Cross M G;Hamnett A et al.[J].Solid State Ionics,1980,1:231.
[38] arouxP et al.[J].Solid State Ionics,1988,27:221.
[39] MiuraN et al.[J].Nihon Kagaku Kaishi(in Japanese),1988,12:1954.
[40] 余双人 .[J].精细与专用化学品,2003(11):30.
[41] MiyakeN;Wainright J S;Savinell R F .[J].Journal of the Electrochemical Society,2001,148:A898.
[42] AdjemianKT;Lee S J;Srinivasan S et al.[J].Journal of the Electrochemical Society,2002,149:A256.
[43] CostamagnaP et al.[J].Electrochimica Acta,2002,47:1023.
[44] Staiti P.;Baglio V.;Lufrano F.;Passalacqua E.;Antonucci V.;Arico AS. .Hybrid Nafion-silica membranes doped with heteropolyacids for application in direct methanol fuel cells[J].Solid state ionics,2001(1/4):101-107.
[45] Tazi;Savadogo O .[J].Electrochimica Acta,2000,45:4329.
[46] YangC;Costamagna P;Srinivasan S et al.[J].Journal of Power Sources,2001,103:1.
[47] ShaoZG;Joghee P et al.[J].Journal of Membrane Science,2004,229:43.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%