通过碳化吸附在SnO2/TiO2电极上的葡萄糖制备出C/SnO2/TiO2纳米复合电极材料.采用晶体粉末衍射仪(XRD)、场发射扫描电镜(SEM)、X射线能谱分析(EDS)等手段对复合电极进行了表征.将复合电极作为锂离子电池负极材料,通过循环伏安和计时电位法研究了其电化学性能.结果表明,在大的电流密度200 μA·cm2下循环30次后,放电容量仍保持在120.1 μAh·cm2.相比SnO2/TiO2电极,C/SnO2/TiO2复合电极电化学性能显著提高,交流阻抗谱图也显示C/SnO2/TiO2纳米复合材料拥有更低的电荷转移电阻.
参考文献
[1] | Abrham K M .Directions in secondary lithium battery research and development[J].Electrochimica Acta,1993,38(9):1233. |
[2] | Natarajan C.;Nogami G.;Setoguchi K. .Preparation of a nanocrystalline titanium dioxide negative electrode for the rechargeable lithium ion battery[J].Electrochimica Acta,1998(21/22):3371-3374. |
[3] | Tarascon J M;Poizot P;Laruelle S et al.Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries[J].NATURE,2000,407(6803):496. |
[4] | Wang, Y;Lee, JY;Zeng, HC .Polycrystalline SnO2 nanotubes prepared via infiltration casting of nanocrystallites and their electrochemical application[J].Chemistry of Materials,2005(15):3899-3903. |
[5] | Jun Song Chen;Yan Ling Cheah;Yuan Ting Chcn .SnO2 Nanoparticles with Controlled Carbon Nanocoating as High-Capacity Anode Materials for Lithium-Ion Batteries[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(47):20504-20508. |
[6] | Endo M.;Nishimura K.;Fujino T.;Miyashita K.;Kim C. .Recent development of carbon materials for Li ion batteries[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(2):183-197. |
[7] | Kim E;Son D;Kim T G et al.A mesoporous/crystalline composite material containing tin phosphate for use as the anode in lithium ion batteries[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2004,43(44):5987. |
[8] | X. W. Lou;Y. Wang;C. Yuan;J. Y. Lee;L. A. Archer .Template-Free Synthesis of SnO2 Hollow Nanostructures with High Lithium Storage Capacity[J].Advanced Materials,2006(17):2325-2329. |
[9] | Liu J P;Li Y Y;Huang X T et al.Direct growth of SnO2 nanorod array electrode forlithium-ion batteries[J].Journal of Materials Chemistry,2009,19:1859. |
[10] | 王红强,季晶晶,赵欣,张经济,李玉,李庆余,黄有国.三维多孔C球包覆纳米SnO2复合材料的电化学性能研究[J].材料导报,2013(08):48-51. |
[11] | Min-Sik Park;Guo-Xiu Wang;Yong-Mook Kang .Preparation and Electrochemical Properties of SnO_2 Nanowires for Application in Lithium-Ion Batteries[J].Angewandte Chemie,2007(5):750-753. |
[12] | 李鹏飞,李岩,王凤平,胡建玲,李泉水,徐美,邱红梅,潘礼庆.蠕虫状SnO2纳米管的水热方法制备和光学性能研究[J].材料导报,2012(24):57-59. |
[13] | Wang, Z.;Luan, D.;Boey, F.Y.C.;Lou, X.W. .Fast formation of SnO2 nanoboxes with enhanced lithium storage capability[J].Journal of the American Chemical Society,2011(13):4738-4741. |
[14] | Rong Yang;Wei Zhao;Jie Zheng .One-Step Synthesis of Carbon-Coated Tin Dioxide Nanoparticles for High Lithium Storage[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(47):20272-20276. |
[15] | 徐勤勤,李娟,孙猛,于航,肖广全.超声波-TiO2光催化处理对垃圾渗滤液氨氮和COD去除的研究[J].三峡环境与生态,2011(02):27-30,42. |
[16] | Dawei Liu;Yunhuai Zhang;Peng Xiao;Betzaida Batalla Garcia;Qifeng Zhang;Xiaoyuan Zhou;Yoon-Ha Jeong;Guozhong Cao .TiO_2 nanotube arrays annealed in CO exhibiting high performance for lithium ion intercalation[J].Electrochimica Acta,2009(27):6816-6820. |
[17] | Dawei Liu;Peng Xiao;Yunhuai Zhang .TiO2 Nanotube Arrays Annealed in N2 for Efficient Lithium-Ion Intercalation[J].The journal of physical chemistry. C, Nanomaterials and interfaces,2008(30):11175-11180. |
[18] | Xiao P;Garcia BB;Guo Q;Liu DW;Cao GZ .TiO2 nanotube arrays fabricated by anodization in different electrolytes for biosensing[J].Electrochemistry communications,2007(9):2441-2447. |
[19] | Jinping Liu;Yuanyuan Li;Ruimin Ding .Carbon/ZnO Nanorod Array Electrode with Significantly Improved Lithium Storage Capability[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(13):5336-5339. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%