欢迎登录材料期刊网

材料期刊网

高级检索

采用粉末冶金法对40(50Cu-Ni)-(NiFe2O4-10NiO)金属陶瓷进行MnO掺杂实验,并对不同添加量试样进行烧结致密化与电解腐蚀性能研究。结果表明:在烧结过程中Mn2+会取代部分基体尖晶石中Ni2+发生晶格畸变,提高烧结活性,当添加量为3wt%时,试样收缩率为18.5%,致密度达97.7%;24 h杂质含量最低,电解24 h后铝液中的Cu、Fe、Ni、Mn的杂质含量最低,分别为0.069wt%、0.121wt%、0.115wt%、0.028wt%。

The modification experiments focuses on the 40(50Cu-Ni)-(NiFe2O4-10NiO) with MnO in powder metallurgy, The density and corrosion of electricity were studied by different amount of sample, results show that Mn2+ replace part of the matrix Ni2+ during sintering, lattice distortion occurs, increasing the sintering activity. The sample is 18. 5% shrinkage rate when the addition amount of 3wt%, density up to 97. 7%. The impurity content is lower after 24 h electrolysis,the content of Cu, Ni, Mn in aluminum liquid is 0. 069wt%,0. 121wt%,0. 115wt%,0. 028wt%,respectively.

参考文献

[1] 李劼;赖延清;周科朝;李志友;刘业翔.Preparation and preliminary testing of cermet inert anode for aluminum electrolysis[J].中国有色金属学会会刊(英文版),2003(3):663-670.
[2] Donald R.Sadoway.Inert Anodes for the Hall-Heroult Cell: The Ultimate Materials Challenge[J].JOM,20015(5):34-35.
[3] Yuqiang Tao;Zhiyou Li;Dou Zhang.Microstructural Evolution of a Nickel Ferrite-Copper Alloy Cermet During Sintering and High-Temperature Oxidation[J].Journal of the American Ceramic Society,201210(10):3031-3036.
[4] P. Zarrabian;M. Kalantar;S. S. Ghasemi.Fabrication and Characterization of Nickel Ferrite Based Inert Anodes for Aluminum Electrolysis[J].Journal of Materials Engineering and Performance,20145(5):1656-1664.
[5] 席锦会;刘宜汉;姚广春.MnO2对镍铁尖晶石惰性阳极材料性能的影响[J].功能材料,2005(3):374-376.
[6] 席锦会 .两步烧结制备铝电解惰性阳极材料的研究[D].东北大学,2006.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%