采用等电位空心阴极辉光放电技术对纯钛进行W-Mo二元共渗,通过扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、显微硬度计对试样的结构形貌、渗层成分分布及相组成、硬度进行研究.利用摩擦磨损试验仪对试样的摩擦学性能进行研究,利用电化学腐蚀工作站,研究了W-Mo合金渗层在常温静态条件下,在3.5% NaCl腐蚀介质中的耐蚀性能.结果表明,经W-Mo共渗处理后纯钛表面形成了一层均匀致密的W-Mo改性层,渗层最大厚度达到16.6 μm,最大硬度达到1196HV0.1,是基体的6.85倍.W-Mo共渗后改性层主要由W、Mo、MoTi、TixW1-x相组成.由于表面硬度的大幅提升,试样表面的耐磨性也显著提高,最低摩擦系数仅为0.23,较原始试样的0.516明显减小.测得的试样最低腐蚀速率为0.0016 mm/a,是原始试样的1/230,耐蚀性能也显著提高.
参考文献
[1] | Williams J C;Belov A F;eds.Titanium and Titamium Alloys[M].New York:Plenum Press,1982 |
[2] | Boyer R R .An Overview on the use of titanium in the aerospace industry[J].Materials Science and Engineering A,1996,213:103-104. |
[3] | Shira C;Froes F H.Non-Aerospace Application of Titanium[M].Warrendale:TMS,1998:331. |
[4] | Bloyce A;Morton PH;Bell T .Surface engineering of titanium and titanium alloys[J].SURFACE ENGINEERING,1994,5:835-851. |
[5] | Ani Zhecheva;Wei Sha;Savko Malinov et al.Enhancing the microstrtcture and properties of titanium alloys through nitriding and other surface engineering methods[J].Surface and Coatings Technology,2005,200:2192-2207. |
[6] | GAO Yu-kui .Surface modification of TA2 pure titanium by low energy high current pulsed electron beam treatment[J].Applied Surface Science,2011,257:7455-7460. |
[7] | XU Zhong.Plasma Surface Metallurgy[M].北京:科学出版社,2007 |
[8] | LI Zheng-xian;ZHOU Lian;XU Zhong .Titanium plasma surface metallurgy technology[J].Rare Metals Letters,2004,23(2):26-28. |
[9] | 陈飞.Ti6Al4V合金等电位空心阴极辉光放电W-Mo-C渗层的耐磨性[J].材料热处理学报,2014(05):181-185. |
[10] | Fan Ailan;Qin Lin;Tian Linhai;Tang Bin .Study On Bacteria Adherence Properties Of Mo Surface-modified Layer In Ti_6al_4v Alloy Prepared By Plasma Surface Alloying Technique[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2008(2):419-421. |
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