综述了国内外变压吸附(PSA)分离CH_4/N_2所采用的分子筛吸附剂,包括沸石分子筛(ZMS)与碳分子筛(CMS)的研究和应用状况;介绍了ZMS和CMS的种类及其PSA分离CH_4/N_2的原理和效果;详细阐述了不同种类ZMS的组成、孔结构与其PSA分离CH_4/N_2效果之间的关系;分析了各种不同分子筛PSA分离CH_4/N_2中的优势与不足.具有动力学分离效应的分子筛型吸附刺在分离CH_4/N_2的PSA过程中具有能耗费用低、分离效果较好的优势,因此加强其研发将是今后的发展趋势.
The research and application progress at home and abroad of molecular sieve adsorbents, including zeolite molecular sieves (ZMSs) and carbon molecular sieves (CMSs), used for the separation of CH_4/N_2 by pressure swing adsorption (PSA)are described. The types of ZMSs and CMSs and their corresponding principles and effects of PSA separation for CH_4/N_2 are introduced. The correlations between the compositions and pore structure size of ZMSs and their PSA separation effects are expounded in detail. The advantages and deficiencies in PSA separation with various molecular sieve adsorbents are summarized. Application of the PSA process using molecular sieve as adsorbents, which has a kinetic separation effect, to the separation of CH_4/N_2 enjoys the advantages of low energy cost and satisfactory separation performance. This may inspire the prosperity of research and development of ZMSs and CMSs adsorbents with kinetic separation effect.
参考文献
| [1] | Ruthven D M .Past progress and future challenges in adsorption research[J].Industrial and Engineering Chemistry Research,2000,39:2127. |
| [2] | Reid C R et al.Adsorption of gases on a carbon molecular sieve used for air separation:Linear adsorptives as probes for kinetic selectivity[J].Langmuir,1999,15(09):3206. |
| [3] | Jasra R V et al.Separation of gases by pressure swing adsorption[J].Separation Science and Technology,1991,26(07):885. |
| [4] | Baksh M S A;Yang R T .Unique adsorption properties and potential energy profiles of microporous pillared clays[J].AICHE Journal,1992,38:1357. |
| [5] | Jasra R V et al.Adsorptive bulk separation by zeolite molecular sieves[J].Separation Science and Technology,1988,23(10-11):945. |
| [6] | Grey T J;Travis K P .A comparative simulation study of the adsorption of nitrogen and methane in siliceous heulandite and chabazite[J].Microporous and Mesoporous Materials,2001,48:203. |
| [7] | Barrer R M.Zeolites and clay minerals[M].London,UK:Academic Press,1978 |
| [8] | Steven M Kuznickil;Valerie A Bell .A titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules[J].Nature,2001,412:720. |
| [9] | Ackley M W;Yang R T .Diffusion in ion-exchanged clinoptilolites[J].AICHE Journal,1991,37(11):1645. |
| [10] | Rosario H H;Lourdes D;Gelacio A A .Adsorption equilibria and kinetics of CO_2,CH_4 and N_2 in natural zeolites[J].Separation and Purification Technology,1999,15:163. |
| [11] | Ackley M W et al.Adsorption characteristics of high exchange clinoptilolites[J].Industrial and Engineering Chemistry Research,1991,30:2523. |
| [12] | Jayaraman, A;Yang, RT;Chinn, D;Munson, CL .Tailored clinoptilolites for nitrogen/methane separation[J].Industrial & Engineering Chemistry Research,2005(14):5184-5192. |
| [13] | Habgood H W .Removal of nitrogen from natural gas[P].US,2843219,1958-07-15. |
| [14] | Tumock P H;Kadlec R H .Separation of nitrogen and methane via periodic adsorption[J].AICHE Journal,1971,17:335. |
| [15] | Ackley M W et al.Clinoptilolite:Untapped potential for kinetic gas separations[J].Zeolites,1992,12:780. |
| [16] | Kouvelos, E;Kesore, K;Steriotis, T;Grigoropoulou, H;Bouloubasi, D;Theophilou, N;Tzintzos, S;Kanelopous, N .High pressure N-2/CH4 adsorption measurements in clinoptilolites[J].Microporous and Mesoporous Materials,2007(1/2):106-111. |
| [17] | Habgood H W .The kinetics of molecular sieve action:Sorption of nitrogen-methane mixtures by linde molecular sieve[J].Academy of Chem,1958,36:1384. |
| [18] | Jayaraman A;Hernandez-Maldonado AJ;Yang RT;Chinn D;Munson CL;Mohr DH .Clinoptilolites for nitrogen/methane separation[J].Chemical Engineering Science,2004(12):2407-2417. |
| [19] | Aguilar-Armenta G;Hemandez-Ramirez G .Adsorption kinetics of CO_2,O_2,N_2 and CH_4 in cation-exchanged clinoptilolite[J].Journal of Physical Chemistry B,2001,105:1313. |
| [20] | Nazmul H;Ruthven D M .Chromatographic study of sorption and diffusion in 4A zeolite[J].Journal of Colloid and Interface Science,1986,112(01):154. |
| [21] | Tezel F H;Apotonatos G .Chromatographic study of adsorption for N_2,CO and CH_4 in molecular sieve zeolites[J].Gas Separation and Purification,1993,7(01):11. |
| [22] | Kenneth F;Butwel L .Pressure swing adsorption process[P].US,6497750,2002-12-24. |
| [23] | Kuznicki S M .Preparation of small-pored crystalline titanium molecular sieves[P].US,4938939,1990-07-03. |
| [24] | Kuznicki S M;Bell V A;Petrovic I .Small-pored crystalline titanium molecular sieve zeolites and their use in gas separation processes[P].US,6068682,2000-03-30. |
| [25] | William B .Selective removal of nitrogen from natural gas by pressure swing adsorption[P].US,6444012,2002-09-03. |
| [26] | Chao C C .Selective adsorption on magnesium-containing clinoptilolites[P].US,4964889,1990-10-23. |
| [27] | Delgado J A et al.Adsorption equilibrium of carbon dioxide,methane and nitrogen onto Na-and H-mordenite at high pressures[J].Separation and Purification Technology,2006,48:223. |
| [28] | 徐如人.沸石分子筛的结构与合成[M].长春:吉林大学出版社,1987 |
| [29] | Schroter H J .Carbon molecular sieves for gas separation processes[J].Gas Separation and Purification,1993,7(04):247. |
| [30] | Ackley;Mark W;Yang Ralph T .Kinetic separation by pressure swing adsorption:Method of characteristics model[J].AICHE Journal,1990,36(08):1229. |
| [31] | Fatehi A .Separation of methane-nitrogen mixtures by pressure swing adsorption using a carbon molecular sieve[J].Gas Separation and Purification,1995,9(31):199. |
| [32] | Carlos A.Grande;Simone Cavenati;Francisco A.Da Silva;Alirio E.Rodrigues .Carbon Molecular Sieves for Hydrocarbon Separations by Adsorption[J].Industrial & Engineering Chemistry Research,2005(18):7218-7227. |
| [33] | Simone Cavenati;Carlos A. Grande;Alirio E, Eodrigues .Separation of Methane and Nitrogen by Adsorption on Carbon Molecular Sieve[J].Separation Science and Technology,2005(13):2721-2743. |
| [34] | Grimes R William .Natural gas cleanup:Evaluation of a molecular sieve carbon as a pressure swing adsorbent for the separation of methane/nitrogen mixtures[R].Wyoming,Western Research Institute Laramie,1994. |
| [35] | Dong Fei;Lou Hongmei et al.New concept in the design of pressure-swing adsorption processes for multicomponent gas mixtures[J].Industrial and Engineering Chemistry Research,1999,38(01):233. |
| [36] | Dong Fei;Lou Hongmei;Kodama Akio et al.The Petlyuk PSA process for the separation of ternary gas mixtures:exemplification by separating a mixture of CO_2-CH_4-N_2[J].Separation and Purification Technology,1999,16:159. |
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