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在弱碱性介质中阳极氧化制备LY12铝合金着色膜,用动电位扫描法极化曲线和极化电阻电化学测试技术方法研究了着色膜在中性和酸性介质中的耐蚀性能以及时效腐蚀行为。结果表明,着色膜在中性和酸性介质中均具有良好的钝化性能,耐孔蚀性能也显著提高。结合 X射线衍射、表面形貌和电子能谱探讨橄榄绿色膜层的成分和结构对其耐蚀性能的影响。研究表明,着色膜的厚度约为4 μm,主要由刚玉结构的α-Al2O3构成,膜内富集氧和其它耐蚀元素有利于耐蚀性的提高。

Corrosion performance of olive green film on LY12 Al alloy, prepared electrolytically in 0.2 mol/L NaOH at room temperature, is evaluated by electrochemical techniques including dynamical potential anodic polarization curve and polarization resistance. Good passivity of the color film in both acid and neural media and pitting resistance are demonstrated according to the results. Moreover, the color film also shows good long-term corrosion resistance in various aggressive corrosion solutions. The structure, composition and morphology of the color film are analyzed with the help of X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The color film, a little more 4 μm in thickness, is mainly composed by α-alumina based on XRD. The enrichment of O and other corrosion-resistance elements inside film benefits the corrosion performance of LY12 alloy, also helps the stabilization of film color.

参考文献

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9] Wu M, Sun Y. Development of surface treatment for aluminum and its alloy [J]. Surf. Technol., 2003, 32(3): 13-15
[2](吴敏,孙勇. 铝及其合金表面处理的研究现状 [J]. 表面技术, 2003,32(3): 13-15)
[3]Wang H C, Peng Q, Wang X Y. Corrosion resistance of anodized aluminum oxide film [J]. Corros. Prot., 2006,27(8): 391-393
[4] 王海潮, 彭乔, 王啸宇. 电化学法研究铝阳极氧化膜的抗腐蚀性 [J]. 腐蚀与防护, 2006, 27(8):391-393
[5]Cheng W, Chen R Y, Zheng X, et al. Study on black coloring of aluminum alloy surface [J]. Plat. Finish., 2000,22(6): 5-7
[6](程蔚, 陈日耀, 郑曦等. 铝合金表面着亮黑色的研究 [J]. 电镀与精饰, 2000, 22(6): 5-7)
[7]Zhang Y G. Electrolytic coloring of anodizing aluminum film in ferrous sulfate solution [J]. Light Alloy Process. Technol., 2003, 31: 40-42
[8](张永光. 铝阳极氧化膜在亚铁盐溶液中的电解着色 [J]. 轻合金加工技术, 2003,31: 40-42)
[9]Ding L H, Zhang J, Zheng Y. Plasma-prepared Ni/Al2O3:preparation, characterization and toluene hydrogenation [J]. Inter.J. Chem. React. Eng., 2006, 4: 1-7
[10]Yang Z S, Jia J F, Tian J. Preparation of micro-arc discharge oxidized coating on hot-tip aluminized stainless steel sheet [J]. J. Inorg. Mater.,2004,19(6):1446-1450
[11](杨钟时,贾建峰,田均. 不锈钢表面Al2O3膜的微弧氧化制备 [J].无机化学学报,2004,19(6):1446-1450)
[12]Chen Y Z, Wu S, Shen L R. Study on microstructure of AlN produced by N+ implantation into pure aluminum [J]. Nuclear Technol., 2003, 26(4): 295-298
[13] 陈勇忠, 武胜, 沈丽如. 氮离子注入铝的结构研究 [J]. 核技术, 2003, 26(4):295-298
[14]Chen J M, Qian J F, Ma M. The development of self-healing Al2O3 insulating coating [J]. Surf. Technol., 2002, 31:32-36
[15](湛继明,钱家缚,马梅. 自修复三氧化二铝涂层研究 [J]. 表面技术,2002, 31: 32-36)
[16]Chik H, Xu J M. Nanometric superlattices:non-lithog raphic fabrication, materials, and prospects [J]. Mater.Sci. Eng., 2004, R43: 103-138
[17]Li G Q, Li D, Li J Q. Cerium conversion coating formed on anodized aluminum by cathodic electrolysis [J]. J. Chin. Soc. Corros. Prot., 2001, 21(3): 150-157
[18](李国强, 李荻, 李久青. 铝合金阳极氧化膜上阴极电解沉积的稀土铈转化膜 [J]. 中国腐蚀与防护学报, 2001, 21(3): 150-157 )
[19]Ren J J, Zuo Y. The study on morphology and growth mechanism of pits on anodized aluminum [J]. J. Chin. Soc.,Corros. Prot., 2003, 23(4):198-201
[20] 任建军,左禹. 铝阳极氧化膜的蚀孔形貌与蚀孔生长机理研究 [J]. 中国腐蚀与防护学报, 2003, 23(4):198-201
[21]Zhu Z F. Al Anodic Oxidation and Surface Finishing Techniques [M]. Beijing: Chemical Industry Press 2004
[22](朱祖芳.铝合金阳极氧化与表面处理技术 [M].化学工业出版社,北京,2004)
[23] Hou Z H, Liu J P, Xu Y. Investigation on the components, appearance and structure of high voltage anodization film on aluminum [J]. J. Chin. Soc. Corros. Prot, 2001, 21(3):177-181 
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