采用溶胶-凝胶法(Sol-Gel)制备氧化锌(ZnO)薄膜,研究镀膜层数和退火温度对ZnO薄膜晶体结构、光谱性质及表面形貌的影响.X射线衍射谱测试表明,退火温度为600℃、镀膜层数为10层时制备样品的晶粒尺寸最大,结晶度最好.紫外-可见透过谱发现,样品退火后其透过率曲线变得陡直,光学带隙随退火温度升高而逐渐减小.光致发光谱测试显示,ZnO薄膜的发光谱包含388 nm和394 nm附近的两个主要发光峰,分别对应于本征发射和缺陷发射,其强度随退火温度升高呈现相反的变化.原子力显微照片则显示了随退火温度的升高制备样品表面晶粒的分布趋于均匀而致密.
参考文献
| [1] | Aswin Hongsingthong .ZnO Films with Very High Haze Value for Use as Front Transparent Conductive Oxide Films in Thin-Film Silicon Solar Cells[J].Applied physics express,2010(5):P.051102.1. |
| [2] | Yungryel Ryu;Tae-Seok Lee;Jorge A. Lubguban;Henry W. White;Bong-Jin Kim;Yoon-Soo Park;Chang-Joo Youn .Next generation of oxide photonic devices: ZnO-based ultraviolet light emitting diodes[J].Applied physics letters,2006(24):241108-1-241108-3-0. |
| [3] | Gong H;Hu JQ;Wang JH;Ong CH;Zhu FR .Nano-crystalline Cu-doped ZnO thin film gas sensor for CO[J].Sensors and Actuators, B. Chemical,2006(1):247-251. |
| [4] | 李奉杰,李村,张现利,吴振玉,朱维菊.不同醇溶剂中氧化锌纳米晶的可控制备[J].硅酸盐通报,2012(01):145-149. |
| [5] | Jin-Hong Lee;Bong-Whan Yeo;Byung-Ok Park .Effects of the annealing treatment on electrical and optical properties of ZnO transparent conduction films by ultrasonic spraying pyrolysis[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2004(2):333-337. |
| [6] | Li-Yu Lin;Dae-Eun Kim .Effect of Elevated Annealing Temperature on the Microstructure and Nano-hardness of ZnO Films Deposited by the Sol-gel Process[J].International Journal of Precision Engineering and Manufacturing,2012(11):2005-2009. |
| [7] | WEN Bin,LIU Chaoqian,FEI Weidong,WANG Hualin,LIU Shimin,WANG Nan,CHAI Weiping.Effect of Doped Boron on the Properties of ZnO Thin Films Prepared by Sol-gel Spin Coating[J].高等学校化学研究（英文版）,2014(03):509-512. |
| [8] | V. S. Santhosh;K. Rajendra Babu;M. Deepa .Influence of Fe dopant concentration and annealing temperature on the structural and optical properties of ZnO thin films deposited by sol-gel method[J].Journal of Materials Science. Materials in Electronics,2014(1):224-232. |
| [9] | Muscat J.;Harrison NM.;Wander A. .On the prediction of band gaps from hybrid functional theory[J].Chemical Physics Letters,2001(3-4):397-401. |
| [10] | Mahalingam T.;John VS.;Ravi G.;Sebastian PJ. .Microstructural characterization of electrosynthesized ZnTe thin films[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,2002(4):329-339. |
| [11] | K. Sowri Babu;A. Ramachandra Reddy;Ch. Sujatha;K. Venugopal Reddy .Optimization of UV emission intensity of ZnO nanoparticles by changing the excitation wavelength[J].Materials Letters,2013(May 15):97-100. |
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