简述了国内外环氧树脂封装料中所用TiO2、MgO、Al(OH)3、CaCO3、BN、BeO等填料的特点,包括填料的形状、颗粒大小、密度以及特殊性能.根据封装材料不同发展阶段的要求,重点叙述了SiO2、Al2O3、AlN等3种粉体作为填料及其所制备的封装材料各自的优势.结合国内外研究现状,指出了环氧树脂电子封装材料用填料应朝着纳米化、功能化、低膨胀系数、绿色化、低成本化的方向发展.
参考文献
[1] | Lin CH.;Huang JM.;Wang CS. .Synthesis, characterization and properties of tetramethyl stilbene-based epoxy resins for electronic encapsulation[J].Polymer: The International Journal for the Science and Technology of Polymers,2002(10):2959-2967. |
[2] | Sham M L;Kim J K .Evolution of residual stresses in modified epoxy resins for electronic packaging application[J].Composites Part A:Applied Science and Manufacturing,2004,35:537. |
[3] | Balabanovich A I;Hornung A;Merz D .The effect of a curing agent on the thermal degradation of fire retardant brominated epoxy resins[J].Polymer Degradation and Stability,2004,85:713. |
[4] | 阳范文,赵耀明.电子封装用环氧树脂的研究现状与发展趋势[J].电子工艺技术,2001(06):238-241. |
[5] | Case S L;Emmett P O;Thomas C W .Cure profiles,crosslink density,residual stresses,and adhesion in a model epoxy[J].Polymer,2005,46:10831. |
[6] | Zhang S Y;Ding Y F;Li S J et al.Effect of polymeric structure on the corrosion protection of epoxy coatings[J].Corrosion Science,2002,44:861. |
[7] | 付东升,张康助,孙福林,张强.电器灌注用环氧树脂的研究进展[J].绝缘材料,2003(02):30-33. |
[8] | Lisa M;Charles M .Lukehart zirconium tungstate/polyimide nanocomposites exhibiting reduced coefficient of thermal expansiorL[J].Chemistry of Materials,2005,17:2136. |
[9] | Paavo J .A new concept for making fine line substrate for active component in polymer[J].Microelectronics,2003,34:99. |
[10] | Chaturvedi M;Shen Y L .Thermal expansion of particlefilled plastic encapsulate:A micromechanical characterization[J].Acta Materialia,1998,46(12):4287. |
[11] | 陈平;王德中.环氧树脂及其应用[M].北京:化学工业出版社,2004 |
[12] | Kim G G;Kim J H;Kang J A et al.Study on the pretreatment method of glass-epoxy resin in the presence of TiO2 sol prepared by hydrothermal method[J].Catalysis Communications,2007,8:861. |
[13] | Ramajo L;Reboredo M;Castro M .Dielectric response and relaxation phenomena in composites of epoxy resin with BaTiO3 particles[J].Composites Part A:Applied Science and Manufacturing,2005,36:1267. |
[14] | Cho S D;Lee J Y;Hyun J G et al.Study on epoxy/BaTiO3composite embedded capacitor films(ECFs)for organic substrate applications[J].Materials Science and Engineering B:Solid State Materials for Advanced Technology,2004,110:233. |
[15] | 哈恩华,寇开昌,陈立新.环氧灌封材料的研究进展[J].化工进展,2003(10):1057-1060. |
[16] | Li H Y;Zhang Z S;Ma X F et al.Synthesis and characterization of epoxy resin modified with nano-SiO2 and γ-glycidoxypropyltrimethoxy silane[J].Surface and Coatings Technology,2005,4:423. |
[17] | 简本成,陈燕.氧化铝填料性能对环氧树脂浇注制品性能的影响[J].现代技术陶瓷,2004(01):18-20. |
[18] | Zen X H;Fan H Q;Zhang J .Modeling the Al2O3 particlepolymer composites for the packing of the shock-ware pulsed transducer[J].Sensors and Actuators A-physical,2006,1:9. |
[19] | Zhou T L;Gu M Y;Jin Y P et al.Effects of nano-sized carborundum particles and amino silane coupling agent on the cure reaction kinetics of DGEBA/EMI-2,4 system[J].Polymer,2005,46:6216. |
[20] | Chisholm N;Mahfuz H;Vijaya K et al.Fabrication and mechanical characterization of carbon/SiC-epoxy nanocomposites[J].Computers & Structures,2005,67:115. |
[21] | 李秀清.AlN陶瓷封装的研究现状[J].半导体情报,1999(04):1. |
[22] | Saeed M B;Zhan M S .Adhesive strength of nano-size particles filled thermoplastic polyamides.Part-Ⅱ:Aluminum nitride(AlN)nano-powder-polyimide composite films[J].International Journal of Adhesion and Adhesives,2006,12:365. |
[23] | Pezzotti G;Kamada I;Miki S .Thermal conductivity of AlN/polystyrene interpenetrating networks[J].J Eur Cerarn Soc,2000,20:1197. |
[24] | Teh P L;Mariatti M et al.The properties of epoxy resin coated silica fillers composites[J].Materials Letters,2006,1:3. |
[25] | Zhang X H;Xu W J;Xia X N et al.Toughening of cycloaliphatic epoxy resin by nanosize silicon dioxide[J].Materials Letters,2006,60:3319. |
[26] | 张文栓,罗运军,赵辉,李根臣,刘晓飞,徐洪霞,高永忠.纳米SiO2-x改性环氧复合材料研究[J].热固性树脂,2003(04):10-13. |
[27] | 景晓燕,刘晓冬,崔向红.填料在环氧树脂浇注料中的应用[J].化学工程师,2004(11):60-61. |
[28] | Wang J J;Yi X S .Effects of interfacial thermal barrier resistance and particle shape and size on the thermal conductivity of AlN/PI composites[J].Computer Science & Technology,2004,64:1623. |
[29] | Xie SH;Zhu BK;Li JB;Wei XZ;Xu ZK .Preparation and properties of polyimide/aluminum nitride composites[J].Polymer Testing,2004(7):797-801. |
[30] | Goyal RK;Negi YS;Tiwari AN .Preparation of high performance composites based on aluminum nitride/poly(ether-ether-ketone) and their properties[J].European Polymer Journal,2005(9):2034-2044. |
[31] | 刘庆华,李亚东.超细AlN填充环氧树脂热性能研究[J].传感器技术,2005(11):36-38. |
[32] | Hsiue G H;Wei H F;Shiao S J et al.Chemical modification of dicyclopentadiene-based epoxy resins to improve compatiliblity and thermal properties[J].Polymer Degradation and Stability,2001,73:309. |
[33] | Han SO.;Drzal LT. .Curing characteristics of carboxyl functionalized glucose resin and epoxy resin[J].European Polymer Journal,2003(7):1377-1384. |
[34] | Kim GG;Kang JA;Kim JH;Kim SJ;Lee NH;Kim SJ .Metallization of polymer through a novel surface modification applying a photocatalytic reaction[J].Surface & Coatings Technology,2006(6):3761-3766. |
[35] | Frohlich J;Kautz H;Thomann R et al.Reactive core/shell type hyperhbranched blockcopolyethers as new liquid rubbers for epoxy toughening[J].Polymer,2004,45:2155. |
[36] | Xu K;Chen M C;Zhang K et al.Syntheses and characterization of novel epoxy resin bearing naphthyl and limonene moieties,and its cured polymer[J].Polymer,2004,45:1133. |
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