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The results of this work prove that electrochemical reactions are involved in the whole corrosion process of pure Fe with a solid NaCl deposit in water vapor at 600 degrees C. The interaction of chemical and electrochemical reactions accelerates the corrosion rate of pure Fe significantly. The electrochemical reaction is coupled with a preceding chemical reaction process (ce), in which Fe first reacts chemically with NaCl and water vapor to generate HCl(g). And then, the electrochemical reaction proceeds via a one-electron electrochemical reduction to form H(2). (C) 2009 Elsevier B.V. All rights reserved.