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以钇稳定四方氧化锆(Y-TZP)、Al2O3、纳米级的TiC为主要原料,采用真空热压烧结工艺,制备了ZrO2-Al2O3-TiC纳微米复合陶瓷模具材料.研究了该材料的力学性能和微观结构.研究结果表明:当TiC含量为20vol%,Y2O3含量为3mol%时,制备的ZrO2-Al2O3-TiC复合陶瓷模具材料具有良好的力学性能.抗弯强度、断裂韧性和硬度分别达到824 MPa、10.7 MPa·m1/2和11.67 GPa.晶粒细化、穿晶断裂、颗粒桥联、裂纹偏转和相变增韧是主要的增韧补强机理.

参考文献

[1] S. SALEHI;O. VAN DER BIEST;J. VLEUGELS .Electrically conductive ZrO_2-TiN composites[J].Journal of the European Ceramic Society,2006(15):3173-3179.
[2] Eniko Volceanov;Stefania Motoc;Alexandru Traian Abagiu .Influence of sintering environment on zirconia-metal carbides characteristics[J].Journal of the European Ceramic Society,2007(2/3):763-768.
[3] Basu B;Vleugels J;Van der B O .Processing and mechanical properties of ZrO2-TiB2 composites[J].Journal of the European Ceramic Society,2005,25:3629-3637.
[4] Chen T D;Tekeli S L;Dillon R P et al.Phase stability,microstructural evolution and room temperature mechanical properties of TiO2 doped 8 mol% Y2O3 stabilized ZrO2(8Y-CSZ)[J].CERAMICS INTERNATIONAL,2008,34:365-370.
[5] Bamba N;Choa Y;Sekino T et al.Mechanical properties and microstructure for 3 mol% yttria doped zirconia/silicon carbide nanocomposites[J].Journal of the European Ceramic Society,2003,23(04):773-780.
[6] Dongtao Jiang;Omer Van der Biest;Jef Vleugels .ZrO_2-WC nanocomposites with superior properties[J].Journal of the European Ceramic Society,2007(2/3):1247-1251.
[7] Shi J L;Li B S;Yen T S.Mechanical properties of Al2O3 particle-Y-TZP matrix composite and its toughening mechanism[J].Journal of Materials Science,1993(23):4019-4022.
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