Pd and Pd alloy membranes are of increasing interest for hydrogen separation and purification due to their good thermal stability,high permeability and perfect selectivity.PdCu alloy (60wt% Pd) membranes have similar hydrogen permeability compared with PdAg alloy; meanwhile,it is cheaper than PdAg alloy.Furthermore,it has been reported that PdCu membrane has better resistance to poisoning and deactivation by H2S impurity.This paper reviews the properties and manufacturing methods of PdCu alloy membrane,finally,introduced some achievement made by us on PdCu alloy membrane.
参考文献
[1] | Ram Ramachandran;Raghu K. Menon .An overview of industrial uses of hydrogen[J].International journal of hydrogen energy,1998(7):593-598. |
[2] | S.N.Paglieri;J.D.Way .Innovations in palladium membrane research[J].Separation and Purification Methods,2002(1):1-169. |
[3] | Cheng YS.;Pena MA.;Fierro JL.;Hui DCW.;Yeung KL. .Performance of alumina, zeolite, palladium, Pd-Ag alloy membranes for hydrogen separation from Towngas mixture[J].Journal of Membrane Science,2002(1/2):329-340. |
[4] | Roland Dittmeyer;Volker Hollein;Kristian Daub .Membrane reactors for hydrogenation and dehydrogenation processes based ons upported palladium[J].Journal of molecular catalysis, A. Chemical,2001(1/2):135-184. |
[5] | Lattin W C;Utgikar V P .Transition to hydrogen energy in the United States:a 2006 status report[J].International Journal of Hydrogen Energy,2007,32:3230-3237. |
[6] | Wang Z M;Li V;Chan S L I .Review of alloy membranes/films for hydrogen separation or purification[J].Journal of the Chinese Rare Earth Society,2005,23:611-616. |
[7] | Miyazaki J;Kajiyama T;Matsumoto K et al.Ultra high purity hydrogen gas supply system with liquid hydrogen[J].International Journal of Hydrogen Energy,1996,21:335-341. |
[8] | Shu J;Grandjeann B P A;Ghali E et al.Simultaneous deposition of Pd and Ag on porous stainless steel by electrolessplating[J].Journal of Membrane Science,1993,77:181. |
[9] | Jayaraman V.;Lin YS. .SYNTHESIS AND HYDROGEN PERMEATION PROPERTIES OF ULTRATHIN PALLADIUM-SILVER ALLOY MEMBRANES[J].Journal of Membrane Science,1995(3):251-262. |
[10] | Shu J;Adnot A;Grandjean B P A et al.Structurally stable composite Pd-Ag alloy membranes:introduction of diffusion barrier[J].Thin Solid Films,1996,286:72. |
[11] | Uemiya S;Matsuda T;Kikuchi E .Hydrogen permeable palladium-silver alloy membrane supported on porous ceramics[J].Journal of Membrane Science,1991,56:315. |
[12] | Xomeritakis G.;Lin YS. .FABRICATION OF THIN METALLIC MEMBRANES BY MOCVD AND SPUTTERING[J].Journal of Membrane Science,1997(2):217-230. |
[13] | Barbieri G;Violante V;Drioli E .[J].Industrial and Engineering Chemistry Research,1997,36:3369-3374. |
[14] | Shu J;Grandjean B PA;Ghali E et al.[J].Journal of Membrane Science,1993,77:181-195. |
[15] | Hughes R .Composite palladium membranes for catalytic membrane reactors[J].Membrane Technology,2001,131:9-13. |
[16] | Lin Y S .Microporous and dense inorganic membranes:Current status and prospective[J].Separation and Purification Technology,1995,25:39-55. |
[17] | Kluiters S C.A Status re iew on membrane systems for hydrogen separation[M].Petten,The Netherlands:Energy Center of The Netherlands,2004 |
[18] | Shu J;Grandjean B P A;Neste A V et al.Catalytic palladium-based membrane reactors:A review[J].Canadian Journal of Chemical Engineering,1991,69:1036-1060. |
[19] | Fernando Roa;Michael J. Block;J. Douglas Way .The influence of alloy composition on the H_2 flux of composite Pd-Cu membranes[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2002(1/3):411-416. |
[20] | Zhang XL;Wang WP;Liu J;Sheng SS;Xiong GX;Yang WS .Hydrogen transport through thin palladium-copper alloy composite membranes at low temperatures[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(8):1849-1856. |
[21] | Yang JY;Nishimura C;Komaki M .Hydrogen permeation of Pd60Cu40 alloy covered V-15Ni composite membrane in mixed gases containing H2S[J].Journal of Membrane Science,2008(1/2):246-250. |
[22] | Morreale BD;Ciocco MV;Howard BH;Killmeyer RP;Cugini A;Enick RM .Effect of hydrogen-sulfide on the hydrogen permeance of palladium-copper alloys at elevated temperatures[J].Journal of Membrane Science,2004(2):219-224. |
[23] | Yuan Lixiang;Andreas Goldbach;Xu Hengyong .Segregation and H2 transport rate control in body-centered cubic PdCu membranes[J].Journal of Physical Chemistry B,2007,111:10952-10958. |
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