介孔炭材料与活性炭相比具有较大的孔体积和孔径,高的比表面积以及规则的孔道结构,而介孔炭/氧化硅复合材料兼顾了活性炭与介孔材料的优点,因此在吸附大分子有机污染物方面有很好的应用前景.笔者综述了近年来介孔炭,负载/修饰后的介孔炭,介孔炭/氧化硅复合材料的制备和最新研究进展.在制备方面,根据其制备机理的不同可分为硬模板法和软模板法,制备出有序的介孔炭与介孔炭/氧化硅复合材料.在应用方面,重点介绍了介孔炭材料和介孔炭/氧化硅复合材料对大分子有机污染物的吸附性能.进而对介孔炭/氧化硅复合材料在吸附方面的应用进行了展望.
参考文献
| [1] | Crini G .Non-conventional low-cost adsorbents for dye removal: A review[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2006(9):1061-1085. |
| [2] | Lin SH;Juang RS .Adsorption of phenol and its derivatives from water using synthetic resins and low-cost natural adsorbents: A review[J].Journal of Environmental Management,2009(3):1336-1349. |
| [3] | Srivastava VC;Swamy MM;Mall ID;Prasad B;Mishra IM .Adsorptive removal of phenol by bagasse fly ash and activated carbon: Equilibrium, kinetics and thermodynamics[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2006(1/2):89-104. |
| [4] | Caetano, M.;Valderrama, C.;Farran, A.;Cortina, J.L. .Phenol removal from aqueous solution by adsorption and ion exchange mechanisms onto polymeric resins[J].Journal of Colloid and Interface Science,2009(2):402-409. |
| [5] | Bansal R C;Goyal M.Activated carbon adsorption[M].Taylor & Francis Group,LLC,2005 |
| [6] | 徐如人;庞文琴;于吉红.分子筛与多孔材料化学[M].北京:科学出版社,2004 |
| [7] | Beck J S;Vartuli J C;Roth W J et al.A new family of mesoporous molecular sieves prepared with liquid crystal templates[J].Journal of the American Chemical Society,1992,114(27):10834-10843. |
| [8] | Priti A. Mangrulkar;Sanjay P. Kamble;J. Meshram;Sadhana S. Rayalu .Adsorption Of Phenol And O-chlorophenol By Mesoporous Mcm-41[J].Journal of hazardous materials,2008(2/3):414-421. |
| [9] | Kathy A. Northcott;Kiyokazu Miyakawa;Syunichi Oshima .The adsorption of divalent metal cations on mesoporous silicate MCM-41[J].Chemical engineering journal,2010(1):25-28. |
| [10] | An-Hui Lu;Ferdi Schueth .Nanocasting: A Versatile Strategy for Creating Nanostructured Porous Materials[J].Advanced Materials,2006(14):1793-1805. |
| [11] | 宋怀河,李丽霞,陈晓红.有序介孔炭的模板合成进展[J].新型炭材料,2006(04):374-383. |
| [12] | Liu X B;Chang F;Xu L et al.Synthesis and characterization of a new nanoporous carbon material with a bimodal pore system[J].Carbon,2006,44:184-187. |
| [13] | Ryoo R.;Kruk M.;Jaroniec M.;Joo SH. .Ordered mesoporous carbons[J].Advanced Materials,2001(9):677-681. |
| [14] | 黄正宏,王磊,白宇,康飞宇.自组装软模板法制备有序中孔炭研究进展[J].新型炭材料,2012(05):321-336. |
| [15] | 李娜,王先友,易四勇,戴春岭.模板法制备中孔碳材料[J].化学进展,2008(07):1202-1207. |
| [16] | Chengdu Liang;Zuojiang Li;Sheng Dai .Mesoporous Carbon Materials: Synthesis and Modification[J].Angewandte Chemie,2008(20):3696-3717. |
| [17] | Wan Y;Sho Y;Zhao D .Supramolecular aggregates as templates: Ordered mesoporous polymers and carbons[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(3):932-945. |
| [18] | Yonghui Deng;Jing Wei;Zhenkun Sun .Large-pore ordered mesoporous materials templated from non-Pluronic amphiphilic block copolymers[J].Chemical Society Reviews,2013(9):4054-4070. |
| [19] | Li, W.;Zhao, D. .An overview of the synthesis of ordered mesoporous materials (Review)[J].Chemical communications,2013(10):943-946. |
| [20] | Ying Wan;Yifeng Shi;Dongyuan Zhao .Designed synthesis of mesoporous solids via nonionic-surfactant-templating approach[J].Chemical communications,2007(9):897-926. |
| [21] | Ying Wan;Dongyuan Zhao .On the Controllable Soft-Templating Approach to Mesoporous Silicates[J].Chemical Reviews,2007(7):2821-2860. |
| [22] | Wan Y;Yang HF;Zhao DY ."Host-guest" chemistry in the synthesis of ordered nonsiliceous mesoporous materials[J].Accounts of Chemical Research,2006(7):423-432. |
| [23] | Yang HF;Zhao DY .Synthesis of replica mesostructures by the nanocasting strategy[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(12):1217-1231. |
| [24] | Ma T Y;Liu L;Yuan Z Y.Direct synthesis of ordered mesoporous carbons[J].Chemical Society Reviews,2013 |
| [25] | Lee J;Kim J;Hyeon T .Recent progress in the synthesis of porous carbon materials[J].Advanced Materials,2006(16):2073-2094. |
| [26] | Jinwoo Lee;Jaeyun Kim;Taeghwan Hyeon .Synthesis of new nanostructured carbon materials using silica nanostructured templates by Korean research groups[J].International Journal of Nanotechnology,2006(2/3):253-279. |
| [27] | Ruili Liu;Yifeng Shi;Ying Wan .Triconstituent Co-assembly to Ordered Mesostructured Polymer-Silica and Carbon-Silica Nanocomposites and Large-Pore Mesoporous Carbons with High Surface Areas[J].Journal of the American Chemical Society,2006(35):11652-11662. |
| [28] | T. Grant Glover;M. Douglas LeVan .Carbon-silica composite adsorbent: Sensitivity to synthesis conditions[J].Microporous and Mesoporous Materials,2009(1/3):21-27. |
| [29] | Liu, YR .One-pot synthesis of ordered mesoporous carbon-silica nanocomposites templated by mixed amphiphilic block copolymers[J].Journal of Materials Science,2009(13):3600-3607. |
| [30] | Xianbin Liu;Fuxiang Chang;Lei Xu;Yue Yang;Peng Tian;Lihong Qu;Zhongmin Liu .Preparation of ordered carbon/silica hybrid mesoporous materials with specific pore size expansion[J].Microporous and Mesoporous Materials,2005(1/3):269-273. |
| [31] | 刘献斌,刘中民,常福祥,曲丽红,桑石云,张阳阳.以含模板剂的中孔MCM-41为模板合成类碳纳米管材料[J].新型炭材料,2006(03):237-242. |
| [32] | Patricia Valle-Vigon;Marta Sevilla;Antonio B. Fuertes .Mesostructured silica-carbon composites synthesized by employing surfactants as carbon source[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2010(1/3):165-174. |
| [33] | L. John Kennedy;J. Judith Vrjaya;K. Kayalvizhi .Adsorption of phenol from aqueous solutions using mesoporous carbon prepared by two-stage process[J].Chemical engineering journal,2007(1/3):279-287. |
| [34] | C. Namasivayam;D. Kavitha .Adsorptive removal of 2-chlorophenol by low-cost coir pith carbon[J].Journal of hazardous materials,2003(1/3):257-274. |
| [35] | Enamul Haque;Nazmul Abedin Khan;Siddulu Naidu Talapaneni .Adsorption of Phenol on Mesoporous Carbon CMK-3: Effect of Textural Properties[J].Bulletin of the Korean Chemical Society,2010(6):1638-1642. |
| [36] | 郭卓,袁悦.介孔碳CMK-3对苯酚的吸附动力学和热力学研究[J].高等学校化学学报,2007(02):289-292. |
| [37] | L. John Kennedy;J. Judith Vijaya;G. Sekaran;K. Kayalvizhi .Equilibrium, kinetic and thermodynamic studies on the adsorption of m-cresol onto micro- and mesoporous carbon[J].Journal of hazardous materials,2007(1):134-143. |
| [38] | Liu GM;Zheng SR;Yin DQ;Xu ZY;Fan J;Jiang F .Adsorption of aqueous alkylphenol ethoxylate surfactants by mesoporous carbon CMK-3[J].Journal of Colloid and Interface Science,2006(1):47-53. |
| [39] | Yuan X;Xing W;Zhuo SP;Si WJ;Gao XL;Han ZH;Yan ZF .Adsorption of bulky molecules of nonylphenol ethoxylate on ordered mesoporous carbons[J].Journal of Colloid and Interface Science,2008(2):558-565. |
| [40] | Qian Sui,Jun Huang,Yousong Liu,Xiaofeng Chang,Guangbin Ji,Shubo Deng,Tao Xie,Gang Yu.Rapid removal of bisphenol A on highly ordered mesoporous carbon[J].环境科学学报（英文版）,2011(02):177-182. |
| [41] | Adam W. Marczewski .Kinetics and equilibrium of adsorption of organic solutes on mesoporous carbons[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(13):5818-5826. |
| [42] | Xin Zhuang;Ying Wan;Cuimiao Feng .Highly Efficient Adsorption of Bulky Dye Molecules in Wastewater on Ordered Mesoporous Carbons[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(4):706-716. |
| [43] | Mohammadi, N.;Khani, H.;Gupta, V.K.;Amereh, E.;Agarwal, S. .Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies[J].Journal of Colloid and Interface Science,2011(2):457-462. |
| [44] | M. Anbia;A. Ghaffari .Removal of Malachite Green from Dye Wastewater Using Mesoporous Carbon Adsorbent[J].Journal of the Iranian Chemical Society,2011(1S):67-76. |
| [45] | RunCang Sun;J. Tomkinson .Fractional separation and physico-chemical analysis of lignins from the black liquor of oil palm trunk fibre pulping[J].Separation and Purification Technology,2001(3):529-539. |
| [46] | V.K.Garg;Rakesh Kumar;Renuka Gupta .Removal of malachite green dye from aqueous solution by adsorption using agro-industry waste: a case study of Prosopis cineraria[J].Dyes and Pigments,2004(1):1-10. |
| [47] | Mall I D;Srivastava V C;Agarwal N K et al.Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon-kinetic study and equilibrium isotherm analyses[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2005,264(1-3):17-28. |
| [48] | Dong X P;Fu J;Jin J H et al.Adsorption of basic dye in aqueous solution by mesoporous carbon materials[J].Advances in Materials Research,2012,441:559-563. |
| [49] | Yong Tian;Ping Liu;Xiufang Wang .Adsorption of malachite green from aqueous solutions onto ordered mesoporous carbons[J].Chemical engineering journal,2011(3):1263-1269. |
| [50] | Fengling Liu;Jiahong Wang;Liyuan Li .Adsorption of Direct Yellow 12 onto Ordered Mesoporous Carbon and Activated Carbon[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2009(11):3043-3050. |
| [51] | Taihong Shi;Yinghong Wen;Chunyu Ma;Shiguo Jia;Zhuochao Wang;Shujian Zou .Adsorption Characteristics of Phenol and Reactive Dyes from Aqueous Solution onto Ordered Mesoporous Carbons Prepared via a Template Synthesis Route[J].Adsorption Science & Technology,2009(7):643-659. |
| [52] | Studies of adsorption equilibria and kinetics in the systems: Aqueous solution of dyes-mesoporous carbons[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(17):5164. |
| [53] | Torkian L;Ashtiani B G;Amereh E et al.Adsorption of Congo red onto mesoporous carbon material:equilibrium and kinetic studies[J].Desalination Water Treat,2012,44(1-3):118-127. |
| [54] | Liu F L;Xu Z Y;Wan H Q et al.Enhanced adsorption of humic acid on ordered mesoporous carbon compared with microporous activated carbon[J].Environmental Toxicology and Chemistry,2011,30(04):793-800. |
| [55] | A. Vinu;K. Z. Hossain;G. Satish Kumar .Adsorption of L-histidine over mesoporous carbon molecular sieves[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(3):530-536. |
| [56] | Hartmann, M;Vinu, A;Chandrasekar, G .Adsorption of vitamin E on mesoporous carbon molecular sieves[J].Chemistry of Materials,2005(4):829-833. |
| [57] | 胡龙兴,党松涛,杨霞萍.载铜介孔碳CMK-3的制备及其对苯酚的吸附-催化氧化性能[J].物理化学学报,2010(02):373-377. |
| [58] | Zhao HH;Liu ZY;Sun DK .TPO-TPD study of an activated carbon-supported copper catalyst-sorbent used for catalytic dry oxidation of phenol[J].Journal of Catalysis,2004(2):297-303. |
| [59] | Zhiping Lei;Zhenyu Liu .Behavior of Cu-Ce/AC catalyst-sorbent in dry oxidation of phenol[J].Fuel Processing Technology,2007(6):607-615. |
| [60] | Chi, Y.;Geng, W.;Zhao, L.;Yan, X.;Yuan, Q.;Li, N.;Li, X..Comprehensive study of mesoporous carbon functionalized with carboxylate groups and magnetic nanoparticles as a promising adsorbent[J].Journal of Colloid and Interface Science,2012:366-372. |
| [61] | Yunxia Zhang;Sichao Xu;Yuanyuan Luo .Synthesis of mesoporous carbon capsules encapsulated with magnetite nanoparticles and their application in wastewater treatment[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(11):3664-3671. |
| [62] | Xiaofeng Ling;Jiansheng Li;Wen Zhu;Yaoyao Zhu;Xiuyun Sun;Jinyou Shen;Weiqing Han;Lianjun Wang .Synthesis of nanoscale zero-valent iron/ordered mesoporous carbon for adsorption and synergistic reduction of nitrobenzene[J].Chemosphere: Environmental toxicology and risk assessment,2012(6):655-660. |
| [63] | Yan Dong;Huiming Lin;Fengyu Qu.Synthesis of ferromagnetic ordered mesoporous carbons for bulky dye molecules adsorption[J].Chemical engineering journal,2012:169-177. |
| [64] | Liu N G;Yin L W;Zhang L Y et al.Ferromagnetic Ni decorated ordered mesoporous carbons as magnetically separable adsorbents for methyl orange[J].Materials Chemistry and Physics,2011,131(1-2):52-59. |
| [65] | Yong Tian;Xiufang Wang;Yufang Pan .Simple synthesis of Ni-containing ordered mesoporous carbons and their adsorption/desorption of methylene orange[J].Journal of hazardous materials,2012(Apr.30):361-368. |
| [66] | Mansoor Anbia;Arezoo Ghaffari .Adsorption of phenolic compounds from aqueous solutions using carbon nanoporous adsorbent coated with polymer[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(23):9305-9310. |
| [67] | Jianguo He;Kun Ma;Jun Jin .Preparation and characterization of octyl-modified ordered mesoporous carbon CMK-3 for phenol adsorption[J].Microporous and Mesoporous Materials,2009(1/3):173-177. |
| [68] | Piotr A.Bazuta;An-Hui Lu;Jorg-Joachim Nitz .Surface and pore structure modification of ordered mesoporous carbons via a chemical oxidation approach[J].Microporous and Mesoporous Materials,2008(1/3):266-275. |
| [69] | Chun He;Xijun Hu .Anionic Dye Adsorption on Chemically Modified Ordered Mesoporous Carbons[J].Industrial & Engineering Chemistry Research,2011(24):14070-14083. |
| [70] | Xiaoping Dong;Jie Fu;Xingxing Xiong;Chen Chen .Preparation of hydrophilic mesoporous carbon and its application in dye adsorption[J].Materials Letters,2011(15/16):2486-2488. |
| [71] | Liu FL;GuoZB;ZhengSR et al.Adsorption of tannic acid and phenol on mesoporous carbon acticated by CO2[J].Chemical Engineering Journal,2012,183:244-252. |
| [72] | Peter Branton;An-Hui Lu;Verdi Schuth .The effect of carbon pore structure on the adsorption of cigarette smoke vapour phase compounds[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(4):1005-1011. |
| [73] | Effective nitrosamines trap derived from the in situ carbonized mesoporous silica MCM-41[J].Journal of hazardous materials,2010(1/3):602. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%