以钛酸四正丁酯((C4H9O)4Ti)水解沉淀的钛羟基氧化物和硝酸锶(Sr(NO3)2)为反应原料,以氢氧化钾(KOH)为矿化剂,以乙二醇((HOCH2)2)为溶剂,经200℃溶剂热反应得到了由纳米颗粒自组装形成的SrTiO3片状纳米结构。分别用XRD、SEM、TEM表征SrTiO3粉体的物相结构和微观形貌。通过光催化降解罗丹明B(RhB)对比研究了乙二醇溶剂热合成的纳米颗粒自组装SrTiO3片状纳米结构和水热合成的SrTiO3粉体的光催化性能,结果表明,乙二醇溶剂热合成的SrTiO3自组装片状纳米结构具有更加优异的光催化性能。
Strontium titanate (SrTiO3) nanosheets self-assembled by nanoparticles were successfully synthesized by ethylene glycol solvothermal reaction route with titanium oxide hydroxyl as reaction materials and potassium hydroxide (KOH) as mineralizer at 200℃. The composition and morphology of the synthesized powders were investigated using XRD, SEM and TEM. The photocatalytic activities of the samples synthesized by hydrother- mal and solvothermal method were studied through recording the degradation of Rhodamine B (RhB) in UV. The result shows that the SrTiO3 self-assembly nanosheets perform better photocatalytic activities.
参考文献
[1] | Zhang W.F.;Zhang M.S.;Du Z.L.;Chen W.C.;Yin Z. .Roles of defects and grain sizes in photoluminescence of nanocrystalline SrTiO3[J].Journal of Physics. Condensed Matter,1999(29):5655-5660. |
[2] | Lenggoro I W;Panatarani C;Okuyama K .[J].Materials Science and Engineering B,2004,113:60-66. |
[3] | Chen Y F;Johnson E;Peng X G .[J].Journal of the American Chemical Society,2007,129:1093710947. |
[4] | Mao Y;Banerjee S;Wong S S .[J].Journal of the American Chemical Society,2003,125:15718-15719. |
[5] | Zhou C;Chen G;Li Y X et al.[J].International Jour-nal of Hydrogen Energy,2009,34:2113-2120. |
[6] | Wei X;Xu G;Ren Z H et al.[J].J Chin Electr Microsc Soc,2010,19:549-558. |
[7] | Wang Y W;Xu H;Wang X B.[J].Journal of Physical Chemistry B,2006:110=13835-110=13840. |
[8] | Hui, JF;Xiang, GL;Xu, XX;Zhuang, J;Wang, X .Monodisperse F-Substituted Hydroxyapatite Single-Crystal Nanotubes with Amphiphilic Surface Properties[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2009(13):5614-5616. |
[9] | Xu C X;Wei X;Guo Y M et al.[J].Materials Re-search Bulletin,2009,44:1635-1641. |
[10] | 刘东,余军霞,王元红,喻德忠.钛酸锶粉体的制备及超声降解性能的研究[J].当代化工,2011(03):241-244. |
[11] | Ahuja S;Kutty T R N .[J].Journal of Photochemistry and Photobiology A:Chemistry,1996,97:99-107. |
[12] | Chang C H;Shen Y H .[J].Materials Letters,2006,60:129-132. |
[13] | Wang D F;Kako T;Ye J H .[J].Journal of Physical Chemistry C,2009,113:3785-3792. |
[14] | Wrighton M S;Ellis A B;Wolczanski P T et al.[J].Journal of the American Chemical Society,2009,98:2774-2779. |
[15] | Liu J W;Chen G;Li Z H et al.[J].Journal of Solid State Chemistry,2006,179:3704-3708. |
[16] | Wang D F;Ye J H;Kako T et al.[J].Journal of Physical Chemistry B,2006,110:15824-15830. |
[17] | Puangpetch T;Sreethawong T;Yoshikawa S et al.[J].J MolCatalA:Chem,2008,287:70-79. |
[18] | Jing Y;Jin S;Jia Y Z et al.[J].Journal of Materials Science,2005,40:6315-6317. |
[19] | Wei X;Xu G;Ren Z H et al.[J].Journal of the American Ceramic Society,2008,91:3795-3799. |
[20] | Xu G;Ren Z H;Du P Y et al.[J].Advanced Materials,2005,17:907-910. |
[21] | Baiju K V;Shukla S;Sandhya K S et al.[J].Journal of Physical Chemistry C,2007,111:7612-7622. |
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