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采用前驱体共混改性法,以FeCl2/NH4NO3为改性剂,得到改性酚醛泡沫,经高温炭化/水蒸汽活化制备出改性酚醛基活性炭泡沫.通过氮气吸附、TG、XRD、SEM、FT-IR等技术对产品的物理化学性质进行了表征,结果表明,改性后的炭泡沫比表面积为311.19m2/g,总孔容为9.687mL/g,孔径分布范围广,引入了有益于酸性气体脱除的含氮基团和Fe离子,特别是二者同时存在时可产生交互衍化作用.

参考文献

[1] 陈华辉.现代复合材料[M].北京:中国物资出版社,1998:38.
[2] Lizzo A A;De Barr J A .Effect of surface area and chemisorbed oxygen on the SO2 adsorbtion capacity of activated char[J].Fuel,1996,75(13):1515.
[3] 李开喜,吕春祥,凌立成.活性炭纤维的脱硫性能[J].燃料化学学报,2002(01):89-96.
[4] Mochida I.;Kawano S.;Sakanishi K.;Kori Y.;Yasutake A. Yoshikawa M.;Kishino M. .Regeneration of initial activity of a pitch-based ACF for NO-NH3 reaction at ambient temperature[J].Fuel,1998(15):1741-1746.
[5] Isao Mochida;Shirahama N;Kawano S et al.NO oxidation over activated carbon fiber (ACF).Part 1,extended Kinetic over a pitch based ACF of very large surface area[J].Fuel,2000,79(04):1713.
[6] Shirahama N;Mochida Y K I .Reaction of NO in air at room temperature with urea supported on pitch based activated carbon fiber[J].Applied Catalysis B:Environmental,2004,52:173.
[7] 杨骏兵,康飞宇,黄正宏.过渡族金属对球形活性炭孔结构与吸附性能的影响[J].清华大学学报(自然科学版),2002(05):688-691.
[8] Yoko Nishi;Takaomi Suzuki .Ambient temperature reduction of NO to N2 in ru-tailored carbon subnanospace[J].Journal of Physical Chemistry B,1997,101:1938.
[9] Masaaki Yoshikawaa;Akinori Yasutakeb I M .Low-tempe-rature selective catalytic reduction of NOx by metal oxides supported on active carbon fribers[J].Applied Catalysis A:General,1998,173:239.
[10] Muniz J;Marban G;Fuertes A B .Low-temperature selective catalytic reduction of NO over modified activated carbon fibres[J].Appl Catalysis B:Enviromental,2000,27:27.
[11] Jagtoyen M.;Derbyshire F. .Activated carbons from yellow poplar and white oak by H3PO4 activation[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(7/8):1085-1097.
[12] 杨骏兵,凌立成,吕春祥,刘朗.二茂铁的添加对酚醛树脂基球形活性炭活化特性以及孔径分布的影响[J].离子交换与吸附,2000(02):155-161.
[13] 刘植昌;凌立成;刘朗 .CO2活化对含铁沥青基炭球中孔形成的影响[J].煤炭转化,1999,22(02):71.
[14] 王曦 .酚醛树脂基碳泡沫的制备及其结构控制[D].同济大学,2007.
[15] Biniak S.;Siedlewski J.;Swiatkowski A.;Szymanski G. .THE CHARACTERIZATION OF ACTIVATED CARBONS WITH OXYGEN AND NITROGEN SURFACE GROUPS[J].Carbon: An International Journal Sponsored by the American Carbon Society,1997(12):1799-1810.
[16] Juan Alcaniz Monge;AgustIn Bueno lIpez;Ma Angeles Lillo Rodenas et al.NO adsorption on activated carbon fibers from iron-containing pitc[J].Microp Mesopo Mater,2008,108(1-3):294.
[17] Sada E;Kumazawa H .Chemical reaction accompanying absorption of NO in aqueous mixed solutions of Fe2+EDTA and Na2SO3[J].Industrial Eng Chem Fundamens,1984,23:60.
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