Cu-29%Zn-3%Al合金中存在热弹性马氏体转变。高压电镜(1000—1200kV)观察表明,母相(β′)为DO_3结构,马氏体(M)为18R结构;试样厚处(~1μm)的马氏体片内可见微小棍状晶体堆积成的精细组织,棍状体粗约10nm并有界面分开;马氏体的表面凹凸不平、极不规则。试样薄处的β′-M界面呈平坦状或规则的锯齿状、排列着平行的位错线簇。尽管电镜试样在金相显微镜下观察到转变的可逆性,而在电镜下则只观察到正转变(β′→M)。这可能是因薄箔试样不易储存弹性能的结果。
The martensitic transformation in Cu-29%Zn-3%Al alloy occurs thermoelastically. High voltage TEM observation shows that the parent phase belongs to DO_3 and martensite belongs to 18R in structure. Fine structures of tiny packages with a traverse size of~10nm in martensite plates have been seen at the thicker part of the sample. The boundary between β' and M at the thinner part was flat or sawtooth-like composed parallel dislocation lines: Although the reversibility of the transformation in TEM samples has been observed under an optical microscope, only the β'→M transformation observed on TEM. Probably, the thickness of thiner part of the foil is too small to store enough elastic energy which is the driving force of the reverse transformation.
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