由于纳米结构半导体硫化铜具有独特的物化性质，使其在光电材料方面得到广泛应用。本文根据国内外的最新研究进展介绍了水热法和溶剂热法制备硫化铜各种形貌的影响因素：反应物质、溶剂、反应温度、反应时间。同时介绍了不同形貌的带隙能及降解有机污染物的研究情况。还介绍了其复合材料在光降解有机物的研究进展。最后对硫化铜纳米晶体材料的能带值的可能影响因素及应用前景做了展望，以期对该领域的研究有一定的帮助。
Because the nanostructure semiconductor metal sulfide has the unique physical and chemical properties, making it apply in photoelectric material. Therefore, according to the latest research progress at home and abroad, this paper has a detailed introduces of the factors affecting copper sulfide nanostructures, such as material, solvent, reaction temperature, reaction time. At the same time, we introduced band gap of the different morphology and the research progress of degradation of organic pollutants. Also we introduced the research progress of composite materials photocatalytic degradation of organic matter. Finally, in order to make some achievements on this field has certain help, the affecting factors of the band gap and application prospect of CuS were discussed.
参考文献
| [1] | Moreels, I.;Lambert, K.;Smeets, D.;De Muynck, D.;Nollet, T.;Martins, J.C.;Vanhaecke, F.;Vantomme, A.;Delerue, C.;Allan, G.;Hens, Z..Size-dependent optical properties of colloidal PbS quantum dots[J].ACS nano,200910(10):3023-3030. |
| [2] | Yu, XX;Yu, JG;Cheng, B;Huang, BB.One-Pot Template-Free Synthesis of Monodisperse Zinc Sulfide Hollow Spheres and Their Photocatalytic Properties[J].Chemistry: A European journal,200927(27):6731-6739. |
| [3] | Manickavachagam Muruganandham;Yoshihumi Kusumoto;Chiyo Okamoto.Mineralizer-Assisted Shape-Controlled Synthesis, Characterization, and Photocatalytic Evaluation of CdS Microcrystals[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200945(45):19506-19517. |
| [4] | Kriegel, I.;Jiang, C.;Rodríguez-Fernández, J.;Schaller, R.D.;Talapin, D.V.;Da Como, E.;Feldmann, J..Tuning the excitonic and plasmonic properties of copper chalcogenide nanocrystals[J].Journal of the American Chemical Society,20123(3):1583-1590. |
| [5] | Cordova R.;Gomez H.;Schrebler R.;Cury P.;Orellana M.;Grez P.;Leinen D.;Ramos-Barrado JR.;Del Rio R..Electrosynthesis and electrochemical characterization of a thin phase of CuxS (x -> 2) on ITO electrode[J].Langmuir: The ACS Journal of Surfaces and Colloids,200222(22):8647-8654. |
| [6] | Lim WP;Wong CT;Ang SL;Low HY;Chin WS.Phase-selective synthesis of copper sulfide nanocrystals[J].Chemistry of Materials: A Publication of the American Chemistry Society,200626(26):6170-6177. |
| [7] | Erokhina S.;Erokhin V.;Nicolini C..Microstructure origin of the conductivity differences in aggregated CuS films of different thickness[J].Langmuir: The ACS Journal of Surfaces and Colloids,20033(3):766-771. |
| [8] | Gorai S;Ganguli D;Chaudhuri S.Synthesis of copper sulfides of varying morphologies and stoichiometries controlled by chelating and nonchelating solvents in a solvothermal process[J].Crystal growth & design,20053(3):875-877. |
| [9] | Tanveer, M.;Cao, Chuanbao;Ali, Zulfiqar;Aslam, Imran;Idrees, Faryal;Khan, Waheed S.;But, Faheem K.;Tahir, Muhammad;Mahmood, Nasir.Template free synthesis of CuS nanosheet-based hierarchical microspheres: an efficient natural light driven photocatalyst[J].CrystEngComm,201424(24):5290-5300. |
| [10] | Yu XL;Cao CB;Zhu HS;Li QS;Liu CL;Gong QH.Nanometer-sized copper sulfide hollow spheres with strong optical-limiting properties[J].Advanced functional materials,20078(8):1397-1401. |
| [11] | Lou YB.;Samia ACS.;Cowen J.;Banger K.;Chen XB.;Lee H.;Burda C..Evaluation of the photoinduced electron relaxation dynamics of Cu1.8S quantum dots[J].Physical chemistry chemical physics: PCCP,20036(6):1091-1095. |
| [12] | Yixin Zhao;Clemens Burda.Development of plasmonic semiconductor nanomaterials with copper chalcogenides for a future with sustainable energy materials[J].Energy & environmental science: EES,20122(2):5564-5576. |
| [13] | Wu Y;Wadia C;Ma WL;Sadtler B;Alivisatos AP.Synthesis and photovoltaic application of copper(l) sulfide nanocrystals[J].Nano letters,20088(8):2551-2555. |
| [14] | Lee H;Yoon SW;Kim EJ;Park J.In-situ growth of copper sulfide nanocrystals on multiwalled carbon nanotubes and their application as novel solar cell and amperometric glucose sensor materials[J].Nano letters,20073(3):778-784. |
| [15] | Ku, G.;Zhou, M.;Song, S.;Huang, Q.;Hazle, J.;Li, C..Copper sulfide nanoparticles as a new class of photoacoustic contrast agent for deep tissue imaging at 1064 nm[J].ACS nano,20128(8):7489-7496. |
| [16] | Min-Rui Gao;Yun-Fei Xu;Jun Jiang.Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices[J].Chemical Society Reviews,20137(7):2986-3017. |
| [17] | Peter Leidinger;Radian Popescu;Dagmar Gerthsen.Nanoscale copper sulfide hollow spheres with phase-engineered composition: covellite (CuS), digenite (Cu_(1.8)S), chalcocite (Cu2S)[J].Nanoscale,20116(6):2544-2551. |
| [18] | Qingyi Lu;Feng Gao;Dongyuan Zhao.One-Step Synthesis and Assembly of Copper Sulfide Nanoparticles to Nanowires, Nanotubes, and Nanovesicles by a Simple Organic Amine-Assisted Hydrothermal Process[J].Nano letters,20027(7):725-728. |
| [19] | Ming Xu;Haoyu Wu;Peimei Da.Unconventional 0-, 1-, and 2-dimensional single-crystalline copper sulfide nanostructures[J].Nanoscale,20125(5):1794-1799. |
| [20] | Tong-Yong Ding;Ming-Sheng Wang;Sheng-Ping Guo;Guo-Cong Guo;Jin-Shun Huang.CuS nanoflowers prepared by a polyol route and their photocatalytic property[J].Materials Letters,200830(30):4529-4531. |
| [21] | Roshan H. Kore;Jaideep S. Kulkarni;Santosh K. Haram.Effect of Nonionic Surfactants on the Kinetics of Disproportion of Copper Sulfide Nanoparticles in the Aqueous Sols[J].Chemistry of Materials,20015(5):1789-1793. |
| [22] | Mojtaba Shamsipur;Seied Mahdi Pourmortazavi;Mahmoud Roushani;Seiedeh Somayyeh Hajimirsadeghi.Electrochemical Preparation and Thermal Characterization of Copper Sulfide Nanoparticles[J].Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry,20146/8(6/8):951-958. |
| [23] | Wenjing Lou;Miao Chen;Xiaobo Wang.Size Control of Monodisperse Copper Sulfide Faceted Nanocrystals and Triangular Nanoplates[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200727(27):9658-9663. |
| [24] | Haibin Wu;Wei Chen.Synthesis and reaction temperature-tailored self-assembly of copper sulfide nanoplates[J].Nanoscale,201112(12):5096-5102. |
| [25] | Joyjit Kundu;Debabrata Pradhan.Controlled Synthesis and Catalytic Activity of Copper Sulfide Nanostructured Assemblies with Different Morphologies[J].ACS applied materials & interfaces,20143(3):1823-1834. |
| [26] | Freymeyer, N.J.;Cunningham, P.D.;Jones, E.C.;Golden, B.J.;Wiltrout, A.M.;Plass, K.E..Influence of solvent reducing ability on copper sulfide crystal phase[J].Crystal growth & design,20139(9):4059-4065. |
| [27] | Li Zhao;Fangqi Tao;Zhao Quan;Xianlong Zhou;Yuhong Yuan;Juncheng Hu.Bubble template synthesis of copper sulfide hollow spheres and their applications in lithium ion battery[J].Materials Letters,2012:28-31. |
| [28] | Qin AM;Fang YP;Ou HD;Liu HQ;Su CY.Formation of various morphologies of covellite copper sulfide submicron crystals by a hydrothermal method without surfactant[J].Crystal growth & design,20053(3):855-860. |
| [29] | Mao, JF;Shu, Q;Wen, YQ;Yuan, HY;Xiao, D;Choi, MMF.Facile Fabrication of Porous CuS Nanotubes Using Well-Aligned [Cu(tu)]Cl center dot 1/2H(2)O Nanowire Precursors as Self-Sacrificial Templates[J].Crystal growth & design,20096(6):2546-2548. |
| [30] | Yonghong Ni;Rong Liu;Xiaofeng Cao;Xianwen Wei;Jianming Hong.Preparation and transformation to hollow nanospheres of wrapped CuS nanowires by a simple hydrothermal route[J].Materials Letters,200710(10):1986-1989. |
| [31] | Hui Qi;Jian-Feng Huang;Li-Yun Cao.One-dimensional CuS microstractures prepared by a PVP-assisted microwave hydrothermal method[J].CERAMICS INTERNATIONAL,20123(3):2195-2200. |
| [32] | Roy P;Srivastava SK.Hydrothermal growth of CuS nanowires from Cu-dithiooxamide, a novel single-source precursor[J].Crystal growth & design,20068(8):1921-1926. |
| [33] | 谭志刚 .不同形貌硫化铜微/纳米结构材料的合成及光催化性能研究[D].湘潭大学,2011. |
| [34] | Hui Qi;Jianfeng Huang;Liyun Cao.Controlled synthesis and optical properties of doughnut-aggregated hollow sphere-like CuS[J].CERAMICS INTERNATIONAL,20128(8):6659-6664. |
| [35] | 赵军;王焕伟;孙墨杰;刘春光;田磊;李健.水热法制备CuS二氧化钛纳米管复合电极及光催化有机磷[J].硅酸盐通报,2014(9):2398-2401. |
| [36] | Meng, Nannan;Zhou, Yifeng;Nie, Wangyan;Song, Linyong;Chen, Pengpeng.CuS/MoS2 nanocomposite with high solar photocatalytic activity[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,20157(7) |
| [37] | Zhang, Y.;Tian, J.;Li, H.;Wang, L.;Qin, X.;Asiri, A.M.;Al-Youbi, A.O.;Sun, X..Biomolecule-assisted, environmentally friendly, one-pot synthesis of CuS/reduced graphene oxide nanocomposites with enhanced photocatalytic performance[J].Langmuir: The ACS Journal of Surfaces and Colloids,201235(35):12893-12900. |
| [38] | Saranya, Murugan;Ramachandran, Rajendran;Kollu, Pratap;Jeong, Soon Kwan;Grace, Andrews Nirmala.A template-free facile approach for the synthesis of CuS-rGO nanocomposites towards enhanced photocatalytic reduction of organic contaminants and textile effluents[J].RSC Advances,201521(21):15831-15840. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%