有机-无机金属卤素钙钛矿太阳能电池作为新一代光伏技术已经吸引到众多关注.近期研究表明,不管是在介空结构还是平面异质结结构的钙钛矿电池中,每次钙钛矿效率的重大突破都归因于钙钛矿薄膜质量的提高.钙钛矿太阳能电池与其他多晶薄膜太阳能电池相似,增加晶粒尺寸和减少晶界可以极大的增加器件效率.在本文中,钙钛矿薄膜形貌和结晶度在最优化的热处理过程可以得到极大的改善和提高.我们制备的高性能平面异质结钙结构钙钛矿太阳能电池,获得了17.81%的最高效率和17.44% ±0.5%的平均效率.
参考文献
[1] | Martin A. Green;Anita Ho-Baillie;Henry J. Snaith.The emergence of perovskite solar cells[J].Nature photonics,20147(7):506-514. |
[2] | Julian Burschka;Norman Pellet;Soo-Jin Moon;Robin Humphry-Baker;Peng Gao;Mohammad K. Nazeeruddin;Michael Graetzel.Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J].Nature,2013Jul.18 TN.7458(Jul.18 TN.7458):316-319. |
[3] | Dong, Qingfeng;Fang, Yanjun;Shao, Yuchuan;Mulligan, Padhraic;Qiu, Jie;Cao, Lei;Huang, Jinsong.Electron-hole diffusion lengths > 175 mu m in solution-grown CH3NH3PbI3 single crystals[J].Science,2015Feb.27 TN.6225(Feb.27 TN.6225):967-970. |
[4] | Yang, Woon Seok;Noh, Jun Hong;Jeon, Nam Joong;Kim, Young Chan;Ryu, Seungchan;Seo, Jangwon;Seok, Sang Il.High-performance photovoltaic perovskite layers fabricated through intramolecular exchange[J].Science,2015Jun.12 TN.6240(Jun.12 TN.6240):1234-1237. |
[5] | Ferrage, Fabien;Cowburn, David;Ghose, Ranajeet.Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells[J].Journal of the American Chemical Society,200917(17):6050-6051. |
[6] | Mingzhen Liu;Michael B. Johnston;Henry J. Snaith.Efficient planar heterojunction perovskite solar cells by vapour deposition[J].Nature,2013Sep.19 TN.7467(Sep.19 TN.7467):395-A2. |
[7] | Jeon, Nam Joong;Noh, Jun Hong;Yang, Woon Seok;Kim, Young Chan;Ryu, Seungchan;Seo, Jangwon;Seok, Sang Il.Compositional engineering of perovskite materials for high-performance solar cells[J].Nature,2015Jan.22 TN.7535(Jan.22 TN.7535):476-a1. |
[8] | Guichuan Xing;Nripan Mathews;Shuangyong Sun;Swee Sien Lim;Yeng Ming Lam;Michael Graetzel;Subodh Mhaisalkar;Tze Chien Sum.Long-Range Balanced Electron-and Hole-Transport Lengths in Organic-Inorganic CH_3NH_3Pbl_3[J].Science,2013Oct.18 TN.6156(Oct.18 TN.6156):344-347. |
[9] | Cites E. Eperon;Victor M. Burlakov;Pablo Docampo;Alain Goriely;Henry J. Snaith.Morphological Control for High performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells[J].Advanced functional materials,20141(1):151-157. |
[10] | Hak-Beom Kim;Hyosung Choi;Jaeki Jeong.Mixed solvents for the optimization of morphology in solution-processed, inverted-type perovskite/ fullerene hybrid solar cells[J].Nanoscale,201412(12):6679-6683. |
[11] | Tom Baikie;Yanan Fang;Jeannette M. Kadro.Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)Pbl3 for solid-state sensitised solar cell applications[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201318(18):5628-5641. |
[12] | Jeong-Hyeok Im;Chang-Ryul Lee;Jin-Wook Lee.6.5% efficient perovskite quantum-dot-sensitized solar cell[J].Nanoscale,201110(10):4088-4093. |
[13] | Jingbi You;Yang (Michael) Yang;Ziruo Hong;Tze-Bin Song;Lei Meng;Yongsheng Liu;Chengyang Jiang;Huanping Zhou;Wei-Hsuan Chang;Gang Li;Yang Yang.Moisture assisted perovskite film growth for high performance solar cells[J].Applied physics letters,201418(18):183902-1-183902-5. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%