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以聚乙二醇(PEG)为造孔剂,采用溶胶-凝胶法制备了多孔纳米TiO_2粉末,并对样品进行了氮吸附测试和X射线衍射分析.结果表明:煅烧过程中,聚乙二醇的受热分解在TiO_2颗粒中形成了4~6 nm的中孔结构;600 ℃煅烧的TiO_2样品均呈单一的锐钛矿相结构,且适量聚乙二醇的加入可抑制TiO_2粒径的长大.光催化降解罗丹明B表明:催化剂具有很强的氧化能力,适量聚乙二醇的加入可提高TiO_2的光催化性能,在本实验进行的条件下,PEG最佳加入量为0.50 g.

参考文献

[1] Asahi R;Morikawa T;Ohwaki T et al.Visible-light Photocatalysis in Nitrogen-doped Titanium Oxides[J].Science,2001,293(5528):269-271.
[2] 吴玉程,宋林云,李云,李勇,李广海,郑治祥.Ce掺杂TiO2纳米粉体的制备及其光催化性能研究[J].人工晶体学报,2008(02):427-430.
[3] Vione D;Minero C;Maurino V;Carlotti AE;Picatonotto T;Pelizzetti E .Degradation of phenol and benzoic acid in the presence of a TiO2-based heterogeneous photocatalyst[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2005(1/2):79-88.
[4] Stylidi M.;Kondarides DI.;Verykios XE. .Visible light-induced photocatalytic degradation of Acid Orange 7 in aqueous TiO2 suspensions[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2004(3):189-201.
[5] S. Matsuzawa;C. Maneerat;Y. Hayata .Immobilization of TiO2 nanoparticles on polymeric substrates by using electrostatic interaction in the aqueous phase[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(1/2):39-45.
[6] Zhang XW;Zhou MH;Lei L .Preparation of photocatalytic TiO2 coatings of nanosized particles on activated carbon by AP-MOCVD[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(8):1700-1708.
[7] Yang Liu;Yan Li;YuntaoWang;Lei Xie;Jie Zheng;Xingguo Li .Sonochemical synthesis and photocatalytic activity of meso- and macro-porous TiO_2 for oxidation of toluene[J].Journal of hazardous materials,2008(1):153-157.
[8] 刘国光,张锋,谢友海,姚琨,牛新书,李红花.Zr/TiO2纳米颗粒的制备及其光催化活性[J].环境科学学报,2006(05):846-850.
[9] Wu T X;Lu G M;Zhao J C .Photoassisted Degradation of Dye Pollutants.V Self-photosensitized Oxidative Transformation of Rhodamine B under Visible Light Irradiation in Aqueous TiO_2 Dispersions[J].Journal of Physical Chemistry B,1998,102:5845-5851.
[10] 祁巧艳,孙剑辉.负载型纳米TiO2光催化降解罗丹明B动力学与机理研究[J].水资源保护,2006(02):56-58,75.
[11] 付宏刚,王建强,任志宇,闫鹏飞,于海涛,辛柏福,袁福龙.Fe3+-TiO2/SiO2薄膜催化剂的结构对其光催化性能影响[J].高等学校化学学报,2003(09):1671-1676.
[12] A.Hosseinnia;M.Keyanpour-Rad;M.Kazemzad .A novel approach for preparation of highly crystalline anatase TiO2 nanopowder from the agglomerates[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2009(3):390-392.
[13] 肖义,党利琴,安丽珍,白士英,雷志斌.中孔石墨碳负载TiO2复合材料光催化降解罗丹明B和苯酚[J].催化学报,2008(01):31-36.
[14] Zhang Z;Wang C;Rama Z et al.Role of Particle Size in Nanocrystalline TiO_2-hased Photocatatysts[J].Journal of Physical Chemistry B,1998,102(52):10871-10878.
[15] Xun He;David Antonelli .Recent Advances in Synthesis and Applications of Transition Metal Containing Mesoporous Molecular Sieves[J].Angewandte Chemie International Edition,2002(2):214-229.
[16] 步绍静,靳正国,刘晓新,杨立荣,程志捷.聚乙二醇含量对纳米TiO2多孔薄膜性质的影响[J].半导体学报,2005(02):329-334.
[17] 符崖,黄岳山,岑人经,范杰.PEG分子量对二氧化钛纳米晶的影响[J].中国医学物理学杂志,2007(01):41-42,45.
[18] 古映莹,邱小勇,杜作娟.不同晶型纳米TiO2的水热合成及光催化性能[J].化工新型材料,2004(03):14-16,39.
[19] 李慧泉,李越湘,周新木,彭绍琴,吕功煊,李树本.La2O3掺杂TiO2光催化剂的制备和性能[J].分子催化,2004(04):304-309.
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