采用Gleeble-3500D热模拟机,研究了电场作用下预设升温速度对Fe-Cu-Ti-C体系燃烧合成的影响.结合X射线衍射分析(XRD)、扫描电镜(SEM)及金相显微镜分析了合成产物的相组成及显微组织,同时基于能量守恒定律对体系中TiC的转化率进行理论计算.结果表明:随着预设升温速度的提高(50~100℃/s),体系的点火温度相应下降(752~629.78℃);试样的致密度则相应地提高;合成产物TiC颗粒逐渐变细.同时转化率计算结果显示:Fe-Cu-Ti-C体系中TiC的转化率随着预设升温速度的提高而有所增加.
By using Gleeble-3500D thermal simulatiou equipment,the effect of preheatinq rate on combustion synthesis of Fe-Cu-Ti-C system unden the action of electrie field was investigated.The phase structure and microstructure of products were analysed by the X-ray diffraction(XRD),scanning electron microscope(SEM) and metallographic microscope.The conversion rate of titanium carbide in Fe-Cu-Ti-C system was calculated basing on the law of conservation of energy.The result shows that the ignition temperature of the system is decreased(from 752℃ to 629.78℃) with the preset heating rate improved(from 50℃/s to 100℃/s);The relative density of the products is also enhanced and the size of titanium carbide becomes smaller and the conversion rate of titanium carbide calculated using theoretical method increases with the preset heating rate increasing.
参考文献
[1] | 刘伯威,樊毅,张金生,高游,吴芳.SiO2和SiC对Cu-Fe基烧结摩擦材料性能的影响[J].中国有色金属学报,2001(z1):110-113. |
[2] | 姚萍屏,熊翔,黄伯云,袁国洲.铜含量对铁基粉末冶金航空刹车材料摩擦磨损性能的影响[J].非金属矿,2001(04):52-53,7. |
[3] | 樊毅,张金生,王零森,高游.铁含量对铜一铁基摩擦材料性能的影响[J].摩擦学学报,1999(03):204. |
[4] | 邓陈虹,葛启录,范爱琴.粉末冶金金属基复合材料的研究现状及发展趋势[J].粉末冶金工业,2011(01):54-59. |
[5] | Z. A. Munir .The effect of external electric fields on the nature and properties of materials synthesized by self-propagating combustion[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2000(2):125-137. |
[6] | 何洪,张丁非,杨屹,冯可芹.电场诱导Fe-Ti-C体系燃烧合成数学模型及机理研究[J].热加工工艺,2010(12):25-27. |
[7] | 计芳,冯可芹,杨屹,连姗姗,吴金岭.工艺参数对电场诱导Fe-Ti-C系燃烧合成的影响[J].材料工程,2007(12):52-57. |
[8] | 冯可芹,杨屹,沈保罗,杨春楣,郭路宝,何洪.电场作用下Fe含量对Fe-Ti-C体系低温燃烧合成的影响[J].稀有金属材料与工程,2004(02):161-165. |
[9] | 冯可芹,白晨光,杨屹.电场诱导Fe-Ti-C体系低温燃烧合成显微组织演变[J].稀有金属材料与工程,2007(06):1020-1023. |
[10] | 冯可芹 .电场诱导燃烧合成铁基复合材料及机理研究[D].四川大学,2004. |
[11] | Kondo, T;Yasuhara, M;Kuramoto, T;Kodera, Y;Ohyanagi, M;Munir, ZA .Effect of pulsed DC current on atomic diffusion of Nb-C diffusion couple[J].Journal of Materials Science,2008(19):6400-6405. |
[12] | Wei-Ming Guo;Jef Vleugels;Guo-Jun Zhang .Effect of heating rate on densification, microstructure and strength of spark plasma sintered ZrB_2-based ceramics[J].Scripta materialia,2010(10):802-805. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%