含氟高分子材料的优异表面性能主要依赖于含氟组分在表面的富集和排列.高分子溶液经常用来制备各种材料,在固化过程中含氟高分子在溶液缔合状态影响含氟组分在表面的富集.文中主要综述了含氟组分组成、结构、溶剂等对含氟聚合物分子在溶液中聚集形态的影响,以及聚合物聚集形态对其固化后表面结构性能影响的研究进展.
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